Synthesis and monolayer film of a series of new twin-tailed gemini cationic surfactants at the air/water interface

• Autorzy: Zhi Chen , Yujun Feng , Dongliang Zhou , Puxin Zhu , Dacheng Wu
• Języki publikacji: EN

Abstrakty

EN

A series of new dimeric surfactants, twin-tailed gemini surfactants, 2(12)-s-2(12), were successfully prepared and characterized, and their monolayer films investigated by the measurement of surface pressure-area (π-A) and surface pressure-time (π-t) isotherms at the air/water interface by a Langmuir film balance. Compared to their monomeric counterparts, their collapse pressure (γcollapse) is smaller, whilst all the molecular area parameters are larger. The limited area (Alimited) and the initial area (Ainitial) of these twin-tailed gemini surfactants change with increasing spacer length s, and the surface pressure decreases with increasing time. It was also found that the higher the initial surface pressure, the larger the attenuation. [...]

Słowa kluczowe

EN

Synthesis; Monolayer; LB films; Twin-tailed gemini surfactant; Isotherms

• Czasopismo: Open Chemistry
• Rocznik: 2008
• Tom: 6
• Numer: 3
• Strony: 477-481

Daty

wydano

2008-09-01

online

2008-08-11

Twórcy

autor

Zhi Chen

autor

Yujun Feng

• Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences, No. 9, Section 4, Renmin South Avenue, Chengdu, 610041, Sichuan, P. R. China,

autor

Dongliang Zhou

• Textile Institute, Sichuan University, Chengdu, 610065, P. R. China

autor

Puxin Zhu

• Textile Institute, Sichuan University, Chengdu, 610065, P. R. China

autor

Dacheng Wu

• Textile Institute, Sichuan University, Chengdu, 610065, P. R. China

Bibliografia

• [1] R. Zana, Adv. Colloid Interface Sci. 97, 205 (2002) http://dx.doi.org/10.1016/S0001-8686(01)00069-0[Crossref]
• [2] R. Zana, J. Xia, “Gemini Surfactants: Synthesis, Interfacial and Solution-Phase Behavior, and Applications”, Marcel Dekker, New York, 2004.
• [3] F. M. Menger, J. S. Keiper, Angew. Chem. Int. Ed. 39, 1906 (2000) http://dx.doi.org/10.1002/1521-3773(20000602)39:11<1906::AID-ANIE1906>3.0.CO;2-Q[Crossref]
• [4] R. Zana, Y. Talmon, Nature 362, 228 (1993) http://dx.doi.org/10.1038/362228a0[Crossref]
• [5] Q. Huo, R. Leon, P.M. Petroff, G.D. Stucky, Science 268, 1324 (1995) http://dx.doi.org/10.1126/science.268.5215.1324[Crossref]
• [6] A. J. Kirby, P. Camilleri, J. B. F. N. Engberts et al., Angew. Chem. Int. Ed. 42, 1448 (2003) http://dx.doi.org/10.1002/anie.200201597[Crossref]
• [7] H. Chen, L. Han, P. Luo, Zh. Ye, Surf. Sci. 552, L53 (2004) http://dx.doi.org/10.1016/j.susc.2004.01.018[Crossref]
• [8] K. Esumi, K. Taguma, Y. Koide, Langmuir 12, 4039 (1996) http://dx.doi.org/10.1021/la960230k[Crossref]
• [9] M. In, V. Bec, O. Aguerre-Chariol, R. Zana, Langmuir 16, 141 (2000) http://dx.doi.org/10.1021/la990645g[Crossref]
• [10] A. Laschewsky, L. Wattebled, M. Arotçaréna, J.-L. Habib-Jiwan, R.H. Rakotoaly, Langmuir 21, 7170 (2005) http://dx.doi.org/10.1021/la050952o[Crossref]
• [11] F. M. Menger, V. A. Migulin, J. Org. Chem. 64, 8916 (1999) http://dx.doi.org/10.1021/jo9912350[Crossref]
• [12] S. Bhattacharya, S. De, J. Chem. Eur. 5, 2335 (1999) http://dx.doi.org/10.1002/(SICI)1521-3765(19990802)5:8<2335::AID-CHEM2335>3.0.CO;2-U[Crossref]
• [13] J. Zhang, B. Jing, Steven L. Regen, Langmuir 21, 8983 (2005) http://dx.doi.org/10.1021/la052031j[Crossref]
• [14] D. Patrycja, D. Anantharaman, N. Osvaldo, Jr. Oliveira, Adv. Colloid Interface Sci. 91, 221 (2001) http://dx.doi.org/10.1016/S0001-8686(99)00034-2[Crossref]
• [15] X. Chen, J. Wang, N. Shen, Y. Luo, L. Li, M. Liu, R.K. Thomas, Langmuir 18, 6222 (2002) http://dx.doi.org/10.1021/la025600l[Crossref]
• [16] F. M. Menger, B. N. A. Mbadugha, J. Am. Chem. Soc. 123, 875 (2001) http://dx.doi.org/10.1021/ja0033178[Crossref]
• [17] S. Martín, P. Cea, G. Pera, M. Haro, M.C López, J. Colloid Interface Sci. 308, 239 (2007) http://dx.doi.org/10.1016/j.jcis.2006.12.080[Crossref]
• [18] Q. Chen, X. Liang, S. Wang, S. Xu, H. Liu, Y. Hu, J. Colloid Interface Sci. 314, 651 (2007) http://dx.doi.org/10.1016/j.jcis.2007.05.063[Crossref]
• [19] H. Yang, P. Zhu, Y. Feng, Z. Chen, D. Zhou, D. Wu, Acta Chimica Sinica 65, 2081 (2007)

Identyfikatory

DOI

10.2478/s11532-008-0031-6