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2008 | 6 | 2 | 237-244
Tytuł artykułu

Kinetics and mechanism of the C-S coupling reactions of aryl Grignard reagents with aryl arenesulfonates

Treść / Zawartość
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
The kinetics of the C-S coupling of arylmagnesium bromides with phenyl tosylate has been studied in THF: toluene at 90°C. The reaction is first order in Grignard reagent and first order in phenyl tosylate. Kinetic data, Hammett relationship and activation parameters are consistent with a nucleophilic addition mechanism involving rate determining attack of carbanion to sulfonyl group followed by a fast phenoxide group leaving. [...]
Wydawca

Czasopismo
Rocznik
Tom
6
Numer
2
Strony
237-244
Opis fizyczny
Daty
wydano
2008-06-01
online
2008-04-17
Twórcy
autor
  • Ankara University, Science Faculty, Beşevler, Ankara, 06100, Turkey
Bibliografia
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Typ dokumentu
Bibliografia
Identyfikatory
Identyfikator YADDA
bwmeta1.element.-psjd-doi-10_2478_s11532-008-0017-4
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