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2007 | 5 | 3 | 824-834
Tytuł artykułu

Pyrrole thin films deposited on paper by pulsed RF plasma

Autorzy
Treść / Zawartość
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Attempts were made to plasma deposit an oriented π-conjugated polymer of pyrrole (Py) on paper surfaces in order to produce electrically conductive layers. The N/C atomic ratio of 0.13–0.24 was observed for all treatment conditions. This implies the nature of the deposition formed on the paper surface via pulsed plasma is different from that of pyrrole monomer. An increase in conductivity of all pyrrole-plasma treated papers was observed. The 50 W RF-power with 5 min plasma exposed paper sample shows 8.15 × 10−9 S·cm−1 conductivity. The conductivity measurements indicated a plasma-enhanced ring-opening reaction mechanism of pyrrole. [...]
Słowa kluczowe
Wydawca

Czasopismo
Rocznik
Tom
5
Numer
3
Strony
824-834
Opis fizyczny
Daty
wydano
2007-09-01
online
2007-09-01
Twórcy
autor
  • Department of Forest Products Engineering, Faculty of Forestry, Suleyman Demirel University, 32260, Isparta, Turkey, sahin@orman.sdu.edu.tr
Bibliografia
  • [1] L.T. Brown, E.H. Le May and E.B. Bursten: Chemistry, The Central Science, Prentice Hall, Englewood Cliffs, New York, 1991.
  • [2] S. Echinger, U. Schmid, F. Teichert, J. Hieber, H. Ritter and M. Hanack: “Attempts to synthesize new low bandgap polymers”, Synthetic Met., Vol. 61(1-2), (1993), pp.163–165. http://dx.doi.org/10.1016/0379-6779(93)91217-P[Crossref]
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  • [12] R.E. Myers: Electrically conductive pyrrole polymers, United States Patent 5407699
  • [13] J.H. Johnston., J. Moraes, T. Borrnann: “Conducting polymers on paper fibres”, International Conference on Science and Technology of Synthetic Metals (Australia), Wollongong, 2004.
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  • [15] K. Tanaka, K. Yoshizawa, T. Takeuchi and T. Yamabe: “Plasma polymerization of thiophene and 3-meyhylythiophene”, Synthetic Met., Vol. 38(1), (1990), pp. 107–116. http://dx.doi.org/10.1016/0379-6779(90)90073-T[Crossref]
  • [16] K. Tanaka and T. Yamabe: “Plasma polymerization of 1-benzothiophene”, J. Appl. Phys., Vol. 70(10), (1991), pp. 5653–5659. http://dx.doi.org/10.1063/1.350181[Crossref]
  • [17] M. Cvetkovska, T. Grchev and T. Obradovic: “Electroconductive polymer composite: Fibrous carrier-polypyrrole”, J. Appl. Polym. Sci., Vol. 60(12), (1996), pp. 2049–2058. http://dx.doi.org/10.1002/(SICI)1097-4628(19960620)60:12<2049::AID-APP2>3.0.CO;2-M[Crossref]
  • [18] J.G. Cruz, J. Morales and R. Olayo: “Films obtained by plasma polymerization of pyrrole”, Thin Solid Films, Vol. 342, (1999), pp. 119–126. http://dx.doi.org/10.1016/S0040-6090(98)01450-3[Crossref]
  • [19] J. Wang, K.G. Neoh and E.T. Kang: “Comparative study of chemically synthesized and plasma polymerized pyrrole and thiophene thin films”, Thin Solid Films, Vol. 446, (2004), pp. 205–217 http://dx.doi.org/10.1016/j.tsf.2003.09.074[Crossref]
  • [20] P. Subramanian, N.B. Clark, R.J.N. Helmer, J.N. Barisci, B.C. Kim, G. Wallace, L. Spiccia and D. Macfarlane: “Electrochromic conducting polymers and packaging products: polymer selection and methods of application”, Appita J., Vol. 59 (6), (2006), pp. 465–470.
  • [21] H.T. Sahin, (unpublished results).
  • [22] H. Yasuda: Plasma polymerization, Academic press, Orlando, 1985.
Typ dokumentu
Bibliografia
Identyfikatory
Identyfikator YADDA
bwmeta1.element.-psjd-doi-10_2478_s11532-007-0025-9
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