Solvent reduced wittig olefination reactions with halo containing conjugated phosphoranes

• Autorzy: Thies Thiemann , Yasuko Tanaka , Keiko Ideta , Shuntaro Mataka
• Języki publikacji: EN

Abstrakty

EN

The Wittig reaction of carbaldehydes with alkoxycarbonylhalomethylidenetriphenylphosphoranes can be performed with ease in solventless systems. The analogous reaction of carbaldehydes with acylhalomethylidenetriphenylphosphoranes requires a small amount of solvent, such as chloroform, in order for the reaction to proceed. The products of the reaction are versatile precursors for further transformations, such as the Suzuki-Miyaura cross-coupling reaction.

Słowa kluczowe

EN

Wittig olefination; solventless reaction; Suzuki-Miyaura cross-coupling

• Czasopismo: Open Chemistry
• Rocznik: 2006
• Tom: 4
• Numer: 3
• Strony: 403-427

Daty

wydano

2006-09-01

online

2006-09-01

Twórcy

autor

Thies Thiemann

• Institute of Materials Chemistry and Engineering, Kyushu University, Kasuyga-shi, Fukuoka, 816-8580, Japan,

autor

Yasuko Tanaka

• Institute of Materials Chemistry and Engineering, Kyushu University, Kasuyga-shi, Fukuoka, 816-8580, Japan

autor

Keiko Ideta

• Institute of Materials Chemistry and Engineering, Kyushu University, Kasuyga-shi, Fukuoka, 816-8580, Japan

autor

Shuntaro Mataka

• Institute of Materials Chemistry and Engineering, Kyushu University, Kasuyga-shi, Fukuoka, 816-8580, Japan

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Identyfikatory

DOI

10.2478/s11532-006-0024-2