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Solvent reduced wittig olefination reactions with halo containing conjugated phosphoranes

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The Wittig reaction of carbaldehydes with alkoxycarbonylhalomethylidenetriphenylphosphoranes can be performed with ease in solventless systems. The analogous reaction of carbaldehydes with acylhalomethylidenetriphenylphosphoranes requires a small amount of solvent, such as chloroform, in order for the reaction to proceed. The products of the reaction are versatile precursors for further transformations, such as the Suzuki-Miyaura cross-coupling reaction.

Opis fizyczny
  • Institute of Materials Chemistry and Engineering, Kyushu University, Kasuyga-shi, Fukuoka, 816-8580, Japan,
  • Institute of Materials Chemistry and Engineering, Kyushu University, Kasuyga-shi, Fukuoka, 816-8580, Japan
  • Institute of Materials Chemistry and Engineering, Kyushu University, Kasuyga-shi, Fukuoka, 816-8580, Japan
  • Institute of Materials Chemistry and Engineering, Kyushu University, Kasuyga-shi, Fukuoka, 816-8580, Japan
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