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2006 | 4 | 2 | 338-350
Tytuł artykułu

Preparation of N-aryl-ketonitrone spin traps

Treść / Zawartość
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
The syntheses of seven N-aryl-C,C-dialkoxycarbonylnitrones 1–7, six of which were original, were achieved from the appropriate aryl-nitroso compounds. These ketonitrones were found to trap efficiently carbon-centred free radicals in aqueous media, yielding stable aminoxyl radicals whose EPR spectra lasted several days. The two penta-deuterated compounds 6 and 7 were also found to be efficient at trapping methoxyl radical. Their various spin adducts showed simple three line signals, very sensitive to the polarity of the environment. This study represents the very first use of linear ketonitrones as spin traps.
Wydawca
Czasopismo
Rocznik
Tom
4
Numer
2
Strony
338-350
Opis fizyczny
Daty
wydano
2006-06-01
online
2006-06-01
Twórcy
autor
  • Laboratoire TRACES, Universités Aix-Marseille 1 et 3, 13397, Marseille, France
  • Laboratoire TRACES, Universités Aix-Marseille 1 et 3, 13397, Marseille, France
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Typ dokumentu
Bibliografia
Identyfikatory
Identyfikator YADDA
bwmeta1.element.-psjd-doi-10_2478_s11532-006-0008-2
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