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2006 | 4 | 2 | 299-316
Tytuł artykułu

Formation and multinuclear magnetic resonance investigation of silylammonium tetracarbonylcobaltate contact ion pairs

Treść / Zawartość
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Silylcobalt tetracarbonyls were reacted with various amines (B) in non-polar solvents to form silylammonium tetracarbonylcobaltate contact ion pairs formulated as [BSiR3+, −Co(CO)4]. The compounds were characterized by IR and multinuclear magnetic resonance spectroscopy both in solution and in solid state. Their properties are analogous to the known ion pairs [BH+, −Co(CO)4] and to amine adducts of halosilanes as well.
Wydawca

Czasopismo
Rocznik
Tom
4
Numer
2
Strony
299-316
Opis fizyczny
Daty
wydano
2006-06-01
online
2006-06-01
Twórcy
autor
  • Research Group for Petrochemistry, Hungarian Academy of Sciences, H-8200, Veszprém, Hungary, sis014@almos.vein.hu
  • Department of Silicate and Materials Engineering, NMR laboratory, University of Veszprém, H-8200, Veszprém, Hungary
Bibliografia
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  • [28] I. Kovács, A. Sisak, F. Ungváry and L. Markó: “On the mechanism of the formation of silyl enol ethers from hydrosilanes and organic carbonyl compounds in the presence of cobalt carbonyls. Kinetic investigation of some reaction steps”, Organometallics, Vol. 7, (1988), pp. 1025–1028. [Crossref]
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Typ dokumentu
Bibliografia
Identyfikatory
Identyfikator YADDA
bwmeta1.element.-psjd-doi-10_2478_s11532-006-0005-5
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