Nowa wersja platformy, zawierająca wyłącznie zasoby pełnotekstowe, jest już dostępna.
Przejdź na


Preferencje help
Widoczny [Schowaj] Abstrakt
Liczba wyników
2014 | 16 | 3 | 12-17
Tytuł artykułu

Anchoring Tri(8-Quinolinolato)Iron Onto Sba-15 for Partial Oxidation of Benzyl Alcohol Using Water as the Solvent

Treść / Zawartość
Warianty tytułu
Języki publikacji
Tri(8-quinolinolato)iron complex immobilized onto SBA-15 catalyst has been synthesized through a stepwise procedure. The characterization results indicated that the BET surface area, total pore volume and average pore width decrease after stepwise modification of SBA-15, while the structure keeps intact. Catalytic tests showed that FeQ3-SBA-15 catalyzes the oxidation reaction well with 34.8% conversion of benzyl alcohol and 74.7% selectivity to benzaldehyde when water is used as the solvent after 1 h reaction. In addition, homogeneous catalyst tri(8-quinolinolato)iron exhibits very bad catalytic behavior using water as the solvent.
Słowa kluczowe

Opis fizyczny
  • Jilin University, Key Laboratory of Surface and Interface Chemistry of Jilin Province, College of Chemistry, Changchun, 130023, PR China
  • Jilin University, Key Laboratory of Surface and Interface Chemistry of Jilin Province, College of Chemistry, Changchun, 130023, PR China
  • Jilin University, Key Laboratory of Surface and Interface Chemistry of Jilin Province, College of Chemistry, Changchun, 130023, PR China
  • Jilin University, Key Laboratory of Surface and Interface Chemistry of Jilin Province, College of Chemistry, Changchun, 130023, PR China,
  • 1. Prakash, S., Charan, C., Singh, A.K. & Shahi, V.K. (2013). Mixed metal nanoparticles loaded catalytic polymer membrane for solvent free selective oxidation of benzyl alcohol to benzaldehyde in a reactor. Appl. Catal. B: Environ. 132, 62-69. DOI: 10.1016/j.apcatb.2012.11.001.[Crossref]
  • 2. Yu, X., Huo, Y., Yang, J., Chang, S., Ma, Y. & Huang, W. (2013). Reduced graphene oxide supported Au nanoparticles as an efficient catalyst for aerobic oxidation of benzyl alcohol. Appl. Surf. Sci. 280, 450-455. DOI: 10.1016/j.apsusc.2013.05.008.[Crossref]
  • 3. Spasiano, D., Prieto Rodriguez, L.D.P., Carbajo Olleros, J., Malato, S., Marotta, R. & Andreozzi, R. (2013). TiO2/Cu(II) photocatalytic production of benzaldehyde from benzyl alcohol in solar pilot plant reactor. Appl. Catal. B: Environ. 136, 56-63. DOI: 10.1016/j.apcatb.2013.01.055.[WoS]
  • 4. Pillai, U.R. & Sahle-Demessie, E. (2004). Selective oxidation of alcohols over vanadium phosphorus oxide catalyst using hydrogen peroxide. Appl. Catal. B: Gen. 276(1-2), 139-144. DOI: 10.1016/j.apcata.2004.07.052.[Crossref]
  • 5. Wang, X., Wu, G., Li, J., Zhao, N., Wei, W. & Sun, Y. (2007). Surface-modified improvement in catalytic performance of Cr(salen) complexes immobilized on MCM-41 in solvent-free selective oxidation of benzyl alcohol. Catal. Lett. 119 (1-2), 87-94. DOI: 10.1007/s10562-007-9197-3.[Crossref][WoS]
  • 6. Habibi, D. & Faraji, A.R. (2013). Synthesis, characterization and application of a nano-manganese-catalyst as an efficient solid catalyst for solvent free selective oxidation of ethylbenzene, cyclohexene, and benzylalcohol. Appl. Surf. Sci. 276, 487-496. DOI: 10.1016/j.apsusc.2013.03.121. [Crossref][WoS]
  • 7. Spasiano, D., Marotta, R., Di Somma, I., Andreozzi, R. & Caprio, V. (2013). Fe(III)-photocatalytic partial oxidation of benzyl alcohol to benzaldehyde under UV-solar simulated radiation. Photochem. Photobiol. Sci. 12 (11), 1991-2000. DOI: 10.1039/c3pp50210d.[Crossref][WoS]
  • 8. Pathan, S. & Patel, A. (2013). Solvent free clean selective oxidation of alcohols catalyzed by mono transition metal (Co, Mn, Ni)-substituted Keggin-phosphomolybdates using hydrogen peroxide. Appl. Catal. B: Gen. 459, 59-64. DOI: 10.1016/j. apcata.2013.03.044.[Crossref][WoS]
  • 9. Zhao, G., Deng, M., Jiang, Y., Hu, H., Huang, J. & Lu, Y. (2013). Microstructured Au/Ni-fiber catalyst: Galvanic reaction preparation and catalytic performance for low-temperature gas- -phase alcohol oxidation. J. Catal. 301, 46-53. DOI: 10.1016/j. jcat.2013.01.020.[Crossref]
  • 10. Shilpa, M.L. & Gayathri, V. (2013). Liquid-phase catalytic oxidation of organic substrates by a recyclable polymer-supported copper(II) complex. Transit. Metal Chem. 38 (6), 705-713. DOI: 10.1007/s11243-013-9740-6.[WoS][Crossref]
  • 11. Zhang, Q., Cai, S., Li, L., Chen, Y., Rong, H., Niu, Z. & Li, Y. (2013). Direct Syntheses of Styryl Ethers from Benzyl Alcohols via Ag Nanoparticle-Catalyzed Tandem Aerobic Oxidation. ACS Catal. 3 (7), 1681-1684. DOI: 10.1021/cs400295h.[Crossref]
  • 12. Sharma, P., Darabdhara, G., Reddy, T.M., Borah, A., Bezboruah, P., Gogoi, P. & Das, M.R. (2013). Synthesis, characterization and catalytic application of Au NPs-reduced graphene oxide composites material: an eco-friendly approach. Catal. Commun. 40, 139-144. DOI: 10.1016/j.catcom.2013.06.021.[WoS][Crossref]
  • 13. Sousa, S.C.A., Bernardo, J.R., Florindo, P.R. & Fernandes, A.C. (2013). Efficient and selective oxidation of alcohols catalyzed by oxo-rhenium complexes. Catal. Commun. 40, 134-138. DOI: 10.1016/j.catcom.2013.06.012.[Crossref]
  • 14. Al Badran, F., Awdry, S. & Kolaczkowski, S.T. (2013). Development of a continuous fl ow reactor for pharmaceuticals using catalytic monoliths: Pt/C selective oxidation of benzyl alcohol. Catal. Today 216, 229-239. DOI: 10.1016/j. cattod.2013.04.017.[Crossref][WoS]
  • 15. Friedrich, H.B., Khan, F., Singh, N. & van Staden, M. (2001). The Ru-Cu-Al-hydrotalcite-catalysed oxidation of alcohols to aldehydes or ketones. Synlett 2001 (6), 869-871. DOI: 10.1055/s-2001-14595.[Crossref]
  • 16. Feng, J., Ma, C., Miedziak, P.J., Edwards, J.K., Brett, G.L., Li, D. & Hutchings, G.J. (2013). Au-Pd nanoalloys supported on Mg-Al mixed metal oxides as a multifunctional catalyst for solvent-free oxidation of benzyl alcohol. Dalton Trans. 42 (40), 14498-14508. DOI: 10.1039/c3dt51855h.[Crossref][WoS]
  • 17. Mandal, S., Santra, C., Bando, K.K., James, O.O., Maity, S., Mehta, D. & Chowdhury, B. (2013). Aerobic oxidation of benzyl alcohol over mesoporous Mn-doped ceria supported Au nanoparticle catalyst. J. Mol. Catal. A: Chem. 378, 47-56. DOI: 10.1016/j.molcata.2013.05.011.[Crossref]
  • 18. Dong, J.J., Unjaroen, D., Mecozzi, F., Harvey, E.C., Saisaha, P., Pijper, D. & Browne, W.R. (2013). Manganese-Catalyzed Selective Oxidation of Aliphatic C-H groups and Secondary Alcohols to Ketones with Hydrogen Peroxide. ChemSusChem 6 (9), 1774-1778. DOI: 10.1002/cssc.201300378.[Crossref][WoS]
  • 19. Ravat, V., Nongwe, I., Meijboom, R., Bepete, G. & Coville, N.J. (2013). Pd on boron-doped hollow carbon spheres - PdO particle size and support effects. J. Catal. 305 (0), 36-45. DOI:[Crossref]
  • 20. Liu, C., Tang, S. & Lei, A. (2013). Oxidant controlled Pd-catalysed selective oxidation of primary alcohols. Chem. Commun. 49 (13), 1324-1326. DOI: 10.1039/C2CC38086B.[Crossref]
  • 21. Cui, W., Zhu, H., Jia, M., Ao, W., Zhang, Y. & Zhaorigetu, B. (2013). One-pot synthesis of imines from benzyl alcohol and amines on Au/ZrO2 catalyst. React. Kinet. Mech. Catal. 109 (2), 551-562. DOI: 10.1007/s11144-013-0576-z.
  • 22. Liu, C., Tang, S. & Lei, A. (2013). Oxidant controlled Pd-catalysed selective oxidation of primary alcohols. Chem. Commun. 49 (13), 1324-1326. DOI: 10.1039/c2cc38086b. [Crossref]
  • 23. Liu, B., Liu, H., Wang, C., Liu, L., Wu, S., Guan, J. & Kan, Q. (2012). Exploration of acid-base geometric infl uence on cooperative activation for aldol reaction. Appl. Catal. A: Gen. 443, 1-7. DOI: 10.1016/j.apcata.2012.06.020.[WoS][Crossref]
  • 24. Li, Z., Liu, L., Hu, J., Liu, H., Wu, S., Huo, Q. & Kan, Q. (2012). Epoxidation of styrene with molecular oxygen catalyzed by a novel oxovanadium(IV) catalyst containing two different kinds of ligands. Appl. Organometal. Chem. 26 (5), 252-257. DOI: 10.1002/aoc.2861.[Crossref][WoS]
  • 25. Rimoldi, M., Fodor, D., van Bokhoven, J.A. & Mezzetti, A. (2013). A stable 16-electron iridium(iii) hydride complex grafted on SBA-15: a single-site catalyst for alkene hydrogenation. Chem. Commun. 49 (96), 11314-6. DOI: 10.1039/c3cc47296e.[WoS][Crossref]
  • 26. Canilho, N., Jacoby, J., Pasc, A., Carteret, C., Dupire, F., Stebe, M.J. & Blin, J.L. (2013). Isocyanate-mediated covalent immobilization of Mucor miehei lipase onto SBA-15 for transesterification reaction. Colloid Surface B 112, 139-45. DOI: 10.1016/j.colsurfb.2013.07.024.[WoS][Crossref]
  • 27. Massah, A.R., Kalbasi, R.J. & Kaviyani, S. (2013). Synthesis, characterization, and application of a manganese Schiff base complex containing salicylaldehyde-poly(vinylamine)/ SBA-15 as a novel heterogeneous hybrid catalyst. RSC Adv. 3 (31), 12816-12825. DOI: 10.1039/c3ra22579h.[Crossref]
  • 28. Erdem, B., Erdem, S., Oksuzoglu, R.M. & Citak, A. (2013). High-surface-area SBA-15-SO3H with enhanced catalytic activity by the addition of poly(ethylene glycol). J. Porous Mat. 20 (5), 1041-1049. DOI: 10.1007/s10934-013-9685-3.
  • 29. Alavi, S., Hosseini-Monfared, H. & Siczek, M. (2013). A new manganese(III) complex anchored onto SBA-15 as efficient catalyst for selective oxidation of cycloalkanes and cyclohexene with hydrogen peroxide. J. Mol. Catal. A: Chem. 377, 16-28. DOI: 10.1016/j.molcata.2013.04.013.[WoS][Crossref]
  • 30. Ma, Z., Wang, X., Wei, S., Yang, H., Zhang, F., Wang, P. & Ma, J. (2013). Cu (I) immobilized on functionalized SBA-15: A recyclable catalyst for the synthesis of 1,3-diynes using terminal alkynes without base. Catal. Commun. 39, 24-29. DOI: 10.1016/j.catcom.2013.04.012.[WoS][Crossref]
  • 31. Zhao, D., Huo, Q., Feng, J., Chmelka, B.F. & Stucky, G. D. (1998). Nonionic Triblock and Star Diblock Copolymer and Oligomeric Surfactant Syntheses of Highly Ordered, Hydrothermally Stable, Mesoporous Silica Structures. J. Am. Chem. Soc. 120 (24), 6024-6036. DOI: 10.1021/ja974025i.[WoS][Crossref]
  • 32. Wu, Z.Y., Wang, H.J., Zhuang, T.T., Sun, L.B., Wang, Y.M. & Zhu, J.H. (2008). Multiple Functionalization of Mesoporous Silica in One-Pot: Direct Synthesis of Aluminum-Containing Plugged SBA-15 from Aqueous Nitrate Solutions. Adv. Funct. Mater. 18 (1), 82-94. DOI: 10.1002/adfm.200700706.[Crossref][WoS]
  • 33. Yang, Y., Ding, H., Hao, S., Zhang, Y. & Kan, Q. (2011). Iron(III), cobalt(II) and copper(II) complexes bearing 8-quinolinol encapsulated in zeolite-Y for the aerobic oxidation of styrene. Appl. Organometal. Chem. 25 (4), 262-269. DOI: 10.1002/aoc.1752.[WoS][Crossref]
  • 34. Mahdavi, V. & Mardani, M. (2012). Selective oxidation of benzyl alcohol with tert-butylhydroperoxide catalysed via Mn (II) 2, 2-bipyridine complexes immobilized over the mesoporous hexagonal molecular sieves (HMS). J. Chem. Sci. 124 (5), 1107-1115. DOI: 10.1007/s12039-012-0307-4. [Crossref][WoS]
Typ dokumentu
Identyfikator YADDA
JavaScript jest wyłączony w Twojej przeglądarce internetowej. Włącz go, a następnie odśwież stronę, aby móc w pełni z niej korzystać.