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2014 | 16 | 2 | 82-86
Tytuł artykułu

Separation of 1,3-Propanediol from Aqueous Solutions by Ion Exchange Chromatography

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1,3-propanediol is a promising monomer with many applications and can be produced by bioconversion of renewable resources. The separation of this product from fermentation broth is a difficult task. In this work, the application of cation exchange resin for the separation of 1,3-propanediol from model aqueous solution was examined. The best effect of separation of 1,3-propanediol from glycerol using sorption method was obtained for H+ resin form, although the observed partition coefficient of 1,3-propanediol was low. On the basis of the results of the sorption of 1,3-propanediol, the ionic forms of the resin were selected and used in the next experiments (H+, Ca2+, Ag+, Na+, Pb2+, Zn2+). The best results in ion exchange chromatography were obtained for cation exchange resin in H+ and Ca2+ form. The use of smaller particle size of resin and a longer length of the column allows to obtain better separation of mixtures.

Opis fizyczny
  • Poznan University of Technology, Institute of Technology and Chemical Engineering, pl. M. Skłodowskiej-Curie 2, 60-965 Poznan, Poland,
  • Poznan University of Technology, Institute of Technology and Chemical Engineering, pl. M. Skłodowskiej-Curie 2, 60-965 Poznan, Poland,
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