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2013 | 15 | 2 | 128-135
Tytuł artykułu

Emulsifiers from renewable materials: an eco-friendly synthesis and properties

Treść / Zawartość
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
The focus of this study was the preparation of novel bio based polyglycerol emulsifiers characterized by a one pot synthesis, thus by modified properties with respect to interfacial activity and effectiveness as emulsion stabilizers. The final products of the esterification process, carried out in the presence of carboxylates were used directly as emulsifiers (without purification or fractionation). Polyglycerol emulsifiers obtained in proposed conditions can be tailored to stabilize the defined emulsion system. The modification of the surface activity of emulsifiers may be obtained by programming the fatty acid acyl group in the polyglycerol ester as well as the hydrocarbon chain length in sodium soap and concentration of this compound in the reaction mixture.
Wydawca

Rocznik
Tom
15
Numer
2
Strony
128-135
Opis fizyczny
Daty
wydano
2013-07-01
online
2013-07-10
Twórcy
  • Gdańsk University of Technology, Department of Fats and Detergents Technology, Chemical Faculty, Gabriela Narutowicza Street 11/12, 80-233 Gdańsk, Poland, halina.szelag@pg.gda.pl
  • Gdańsk University of Technology, Department of Fats and Detergents Technology, Chemical Faculty, Gabriela Narutowicza Street 11/12, 80-233 Gdańsk, Poland, ktd@chem.pg.gda.pl
  • Gdańsk University of Technology, Department of Fats and Detergents Technology, Chemical Faculty, Gabriela Narutowicza Street 11/12, 80-233 Gdańsk, Poland
  • Gdańsk University of Technology, Department of Fats and Detergents Technology, Chemical Faculty, Gabriela Narutowicza Street 11/12, 80-233 Gdańsk, Poland
Bibliografia
  • 1. Lestari, S., Mäki-Arvela, P., Beltramini, J., Max Lu, G.Q. & Murzin, D.Yu. (2009). Transforming triglycerides and fatty acids to biofuels. ChemSusChem. 2, 1109-1119. DOI : 10.1002/ cssc.200900107.[Crossref][WoS]
  • 2. Svensson, M. (2010). Surfactants based on natural fatty acids. In M. Kjellin & I. Johansson (Eds.), Surfactants fromrenewable resources (pp. 3-15), Chichester, John Wiley & Sons Ltd.
  • 3 Garti, N. (2002). Food Emulsifiers: Structure-reactivity relationship, design and applications. In A. Marangoni & S.S. Narine (Eds.), Physical properties of lipids (pp. 265-386). New York, M. Dekker Inc.
  • 4. Zielinski, R.J. (1997). Synthesis and composition of foodgrade emulsifiers. In G. L. Hasenhuettl & R.W. Hartel (Eds.), Food Emulsifiers and Their Applications (pp. 11-38). New York, Chapman & Hall.
  • 5. Kato, T., Nakamura, T., Yamashita, M., Kawaguchi, M., Kato, T. & Itoh, T. (2003). Surfactant properties of purified polyglycerol monolaurate. J. Surfactants Deterg. 6 (4), 331-337. DOI: 10.1007/s11743-003-0278-x.[Crossref]
  • 6. Chun-Hui, (Clayton) Z., Beltramini, J. N., Yong-Xian F. & Max Lu, G.Q. (2008). Chemoselective catalytic conversion of glycerol as a biorenewable source to valuable commodity chemicals. Chem. Soc. Rev. 37, 527-549. DOI: 10.1039/B707343G.[Crossref]
  • 7. García, E., Ferrari, F., García, T., Martínez, M. & Aracil, J. (2001). Optimization of the enzymatic esterification of diglycerol and lauric acid. J. Surfactants Deterg. 4 (3), 257-262. DOI: 10.1007/s11743-001-0177-1.[Crossref]
  • 8. De Meulenaer, B., Vanhoutte, B. & Huyghebaert, A. (2000) Development of chromatographic method for the determination of degree of polymerisation of polyglycerols and polyglycerol fatty acid esters. Chromatographia 51 (1-2), 44-52. DOI: 10.1007/BF02490694.[Crossref]
  • 9. Szeląg, H. & Zwierzykowski, W. (2000). Surface activity of acylglycerol emulsifiers modified with carboxylates. ColloidsSurf., A 164 (1), 63-69. DOI: 10.1016/S0927-7757(99)00393-3.[Crossref]
  • 10. Macierzanka, A. & Szeląg, H. (2010). Structuring of emulsions by tailoring the composition of crystalline emulsifier. In M. Fanun (Ed.), Colloids in Biotechnology (pp. 313-330). London, CRS Press.
  • 11. Sadecka, E. & Szeląg, H. (2012). One-step synthesis of W/O and O/W emulsifiers in the presence of surface active agents. J. Surfact. Deterg. Available under Open Access, DOI: 10.1007/s11743-012-1404-6.[Crossref]
  • 12. Szeląg, H. & Zwierzykowski, W. (1998). Esterification kinetics of glycerol with fatty acids in the presence of sodium and potassium soaps. Fett/Lipid 100(7), 302-307. DOI: 10.1002/(SICI) 1521-4133(199807)100:7<302::AID-LIPI302>3.0.CO;2-N.[Crossref]
  • 13. Szeląg, H., Szyszko, A. & Kornacka, K. (2005). Polyglycerol esters of lauric acid with defined hydrophile-lipophile properties. Pol. J. Chem. Technol. 7 (2), 66-71. ISSN 1509-8117.
  • 14. Standard Methods for the Analysis of Oils, Fats and Derivatives (1979). IUPAC standard: Determination of the acid value (A.V.) and acidity, Part 1 (section 1 and 2), 6th ed., Oxford Pergamon Press.
  • 15. Mc Clements, D.J. (1999). Characterization of emulsion properties. In D.J. Mc Clement, Food Emulsions: Principles,Practice and Techniques (pp. 295-335). Boca Raton, FL, CRS Press.
  • 16. Macierzanka, A., Szeląg, H, Moschakis, T. & Murray, B. (2006). Phase transitions and microstructure of emulsion systems prepared with acylglycerols/zinc stearate emulsifier Langmuir 22 (6), 2487-2497. DOI: 10.1021/la052937p.[Crossref][PubMed]
  • 17. Szeląg, H. & Zwierzykowski, W. (1999). The behaviour of modified monoacylglycerol emulsifiers in emulsion systems. Colloids Surf., A 155 (2-3), 349-357. DOI: 10.1016/S0927-7757(98)00829-2.[Crossref]
  • 18. Rosen, M.J. & Murphy, D.S. (1991). Effect of the nonaqueous phase on interfacial properties of surfactants. 2. Individual and mixed nonionic surfactants in hydrocarbon/water systems. Langmuir 7 (11), 2630-2635. DOI: 10.1021/la00059a039.[Crossref]
  • 19. Awad, T.S. & Sato, K. (2002). Fat crystallization in O/W emulsions controlled by hydrophobic emulsifier additives. In A. Marangoni & S.S. Narine (Eds.), Physical Properties of Lipids (pp. 37-62). New York, M. Dekker Inc.
  • 20. Sakamoto, M., Ohba, A., Kuriyama, J., Maruo, K., Ueno, S. & Sato, K. (2004). Influences of fatty acid moiety and esterification of polyglycerol fatty acid esters on the crystallization of palm mid fraction in oil-in-water emulsion. Colloids Surf.,B 37 (1-2), 27-33. DOI: 10.1016/j.colsurfb.2004.05.017.[Crossref]
  • 21. Duerr-Auster, N., Kohlbrecher, J., Zuercher, T., Gunde, R., Fischer, P. & Windhab, E. (2007). Microstructure and stability of a lamellar liquid crystalline and gel phase formed by a polyglycerol ester Mixture in dilute aqueous solution. Langmuir 23 (26), 12827-12834. DOI: 10.1021/la702242v.[Crossref][WoS]
Typ dokumentu
Bibliografia
Identyfikatory
Identyfikator YADDA
bwmeta1.element.-psjd-doi-10_2478_pjct-2013-0035
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