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2013 | 15 | 2 | 73-80
Tytuł artykułu

Study of the anatase to rutile transformation kinetics of the modified TiO2

Treść / Zawartość
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
TiO2 attracts much interest because of its many potential applications. The use of titanium dioxide strongly depends on its polymorphic form: brookite, anatase, or rutile. Only rutile and anatase play an important role in industry. Anatase as a metastable form undergoes a non-reversible transformation into rutile. Understanding the kinetics of phase transformation and the processes of crystal growth of a material is essential for controlling its structure and, thus, its specific properties. The main purpose of this paper is to explain the anatase to rutile recrystallization kinetics in the modified TiO2 calcined from industrial hydrated titanium dioxide. The apparent activation energy of anatase to rutile transformation and the average size of titanium dioxide crystallites were determined for the unmodified TiO2 and TiO2 modified with P, K, Al, B, Zn, Zr, Ce, Sn, or Sb introduced in the amount of 0.5 mol% and 1.0 mol% when recalculated for their oxides. The growth of TiO2 crystallites during calcination was strongly inhibited by P, Ce and Zr, and inhibited to a lesser degree by Al, Sn and Sb. B and Zn did not affect the investigated process and K accelerated crystallites growth. The values of apparent activation energy depending on a modifier formed a relationship: Al
Słowa kluczowe
Wydawca

Rocznik
Tom
15
Numer
2
Strony
73-80
Opis fizyczny
Daty
wydano
2013-07-01
online
2013-07-10
Twórcy
  • West Pomeraniam University of Technology, Szczecin, Institute of Chemical and Environment Engineering ul. Pułaskiego 10, 70-322 Szczecin, Poland
autor
  • West Pomeraniam University of Technology, Szczecin, Institute of Chemical and Environment Engineering ul. Pułaskiego 10, 70-322 Szczecin, Poland, mglen@zut.edu.pl
autor
  • West Pomeraniam University of Technology, Szczecin, Institute of Chemical and Environment Engineering ul. Pułaskiego 10, 70-322 Szczecin, Poland
autor
  • West Pomeraniam University of Technology, Szczecin, Institute of Chemical and Environment Engineering ul. Pułaskiego 10, 70-322 Szczecin, Poland
Bibliografia
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Typ dokumentu
Bibliografia
Identyfikatory
Identyfikator YADDA
bwmeta1.element.-psjd-doi-10_2478_pjct-2013-0026
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