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2013 | 1 | 56-66
Tytuł artykułu

Functional Π-conjugated polymers based on maleimide for photovoltaic applications

Treść / Zawartość
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
A series of new bis-(2-thienyl) maleimide monomers have been synthesized and characterized. The bis-(2- thienyl)maleimide unit has been copolymerized with different aromatic comonomers. Stille coupling polymerizations under various conditions have been utilized. The copolymers were then characterized by size-exclusion chromatography and their optical and electronic properties were investigated by UV-Vis absorption spectroscopy and cyclic voltammetry. All maleimide based copolymers shared similar LUMO energy levels, which are largely determined by the acceptor moiety, and are close to that of PC61BM to be effective for charge dissociation. These low band gap polymers have been tested for photovoltaic applications and have shown moderate photovoltaic performance. Interesting results were obtained by adding the polymer to the P3HT:PC61BM mixture, as a third component. The ternary blend BHJ solar cells showed power conversion efficiencies of 35% exceeding those of the corresponding binary blends.
Słowa kluczowe
Wydawca

Rocznik
Tom
1
Strony
56-66
Opis fizyczny
Daty
otrzymano
2013-05-13
zaakceptowano
2013-09-25
online
2013-12-31
Twórcy
  • LPICM, UMR 7647 CNRS, Ecole polytechnique, route de Saclay,
    91128 Palaiseau Cedex, France
  • Dipartimento di Scienza dei Materiali,
    Universit´r di Milano Bicocca, via R. Cozzi, 53, 20125, Milano, Italy
  • LPICM, UMR 7647 CNRS, Ecole polytechnique, route de Saclay,
    91128 Palaiseau Cedex, France
  • Dipartimento di Scienza dei Materiali,
    Universit´r di Milano Bicocca, via R. Cozzi, 53, 20125, Milano, Italy
  • LPICM, UMR 7647 CNRS, Ecole polytechnique, route de Saclay,
    91128 Palaiseau Cedex, France
  • LPICM, UMR 7647 CNRS, Ecole polytechnique, route de Saclay,
    91128 Palaiseau Cedex, France
  • The Nanotechnology Research laboratory,
    Materials Engineering Department, Al-Quds University,
    East Jerusalem, Palestine
  • Department of Physics, Bethlehem University,
    Bethlehem, Palestine
  • The Nanotechnology Research laboratory,
    Materials Engineering Department, Al-Quds University,
    East Jerusalem, Palestine
  • Dipartimento di Scienza dei Materiali,
    Universit´r di Milano Bicocca, via R. Cozzi, 53, 20125, Milano, Italy
  • Dipartimento di Scienza dei Materiali,
    Universit´r di Milano Bicocca, via R. Cozzi, 53, 20125, Milano, Italy
  • Dipartimento di Scienza dei Materiali,
    Universit´r di Milano Bicocca, via R. Cozzi, 53, 20125, Milano, Italy
  • LPICM, UMR 7647 CNRS, Ecole polytechnique, route de Saclay,
    91128 Palaiseau Cedex, France
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Typ dokumentu
Bibliografia
Identyfikatory
Identyfikator YADDA
bwmeta1.element.-psjd-doi-10_2478_oph-2013-0004
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