New transformation of cycloalkanone acetals by peracids α,ω-dicarboxylic acids synthesis

• Autorzy: Alexander Terent'ev , Sergey Chodykin
• Języki publikacji: EN

Abstrakty

EN

A new process of oxidation of cycloalkanone acetals under the action of in situ generated performic acid has been found. The main products of the reaction are α, ω-dicarboxylic acids obtained with the yield up to 77% depending on the size of acetals ring. The process has been explored and optimized on the example of the dodecanedioic acid synthesis (a valuable industrial product).

Słowa kluczowe

EN

Cycloalkanone acetals; hydrogen peroxide; dodecanedioic acid; dicarboxylic acid; performic acid; enol-ether; oxidation; Baeyer-Villiger rearrangement

• Czasopismo: Open Chemistry
• Rocznik: 2005
• Tom: 3
• Numer: 3
• Strony: 417-431

Daty

wydano

2005-09-01

online

2005-09-01

Twórcy

autor

Alexander Terent'ev

• N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991 Leninsky Prospect 47, Moscow, Russia,

autor

Sergey Chodykin

• N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991 Leninsky Prospect 47, Moscow, Russia

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Identyfikatory

DOI

10.2478/BF02479272