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2005 | 3 | 1 | 104-114
Tytuł artykułu

Excess thermodynamic quantities of D2O water calculated from its Raman O−D stretching spectra

Treść / Zawartość
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Excess thermodynamic functions of D2O water have been calculated from the vibrationally decoupled O−D stretching spectra of very dilute solutions of HOD in H2O. Comparison of the results with reference calorimetric data for water showed a good correspondence for excess heat capacity above the melting point of ice. The excess enthalpy at the melting point also coincides well with latent heat of melting.
Wydawca

Czasopismo
Rocznik
Tom
3
Numer
1
Strony
104-114
Opis fizyczny
Daty
wydano
2005-03-01
online
2005-03-01
Twórcy
  • Department of Quantum Electronics of Faculty of Physics, Sofia University, 1164, Sofia, Bulgaria, mdg@phys.uni-sofia.bg
  • CREST, Japan Science and Technology Corporation (JST), National Institute of Advanced Industrial Science and Technology (AIST), Higashi, 305-8562, Tsukuba, Ibaraki, Japan
  • Department of Metallurgical Engineering, University of Utah, 84112, Salt Lake City, UT, U.S.A.
  • Department of Quantum Electronics of Faculty of Physics, Sofia University, 1164, Sofia, Bulgaria
Bibliografia
  • [1] G.E. Walrafen:Water: A Comprehensive Treatise, Vol. 1, F. Franks, Plenum Press, New York, 1972.
  • [2] Y. Efimov and Y. Naberukhin: “Distribution of Valent Frequencies and Thermodynamics of Hydrogen Bonding in Water, Calculated on the basis of continuos model from its IR Spectra”,Zh. Strukt. Khim., Vol. 41, (2000), pp. 532–539.
  • [3] M. Georgiev, N. Goutev, Z.S. Nickolov, J.J. Ramsden and G. Georgiev: “Thermodynamic parameters of water calculated from its infrared OH stretching spectrum”,Phil. Mag. B, (2002), pp. 1795–1807.
  • [4] D. Eizenberg and W. Kauzmann:The Structure and Properties of Water, Oxford University Press, Oxford, 1969.
  • [5] V. Zhelyaskov, G. Georgiev, Zh. Nickolov and M. Miteva: “Concentration Raman Study of HOD in D2O”,Mol. Phys.,Vol 64, (1988)pp.1133–1144. http://dx.doi.org/10.1080/00268978800100753[Crossref]
  • [6] Hr. Palamarev and G. Georgiev: “Statistical Distributiin of hydrogen-bonded OH oscillators in HOD on the basis of infrared spectra”Vibr. Spectr., Vol. 7, (1994),pp.255–264. http://dx.doi.org/10.1016/0924-2031(94)85015-1[Crossref]
  • [7] Y. Efimov and Y. Naberukhin: “Fluctuation Theory of Hydrogen Bonding in Liquids”,Faraday Disc. Chem Soc., Vol. 85, (1988), pp. 117–123. http://dx.doi.org/10.1039/dc9888500117[Crossref]
  • [8] A.P. Zhukovsky: “Spectroscopic Confirmation of Continuous Model of Water”,J. Struct. Chem., Vol. 17, (1976), pp. 931–932.
  • [9] Hr. Palamarev and G. Georgiev: “Characterization of OH-stretching vibration in HOD based on the fluctuation model of hydrogen bonds and derived structural data”,J. Mol. Struct.,Vol. 378, (1996),pp.237–248. http://dx.doi.org/10.1016/0022-2860(95)09179-3[Crossref]
  • [10] D.E. Hare and C.M. Sorensen: “Raman spectroscopic study of dilute HOD in liquid H2O in the temperature range −31.5 to 160°C,”J. Chem. Phys.,Vol. 93, (1990),pp.6954–6961. http://dx.doi.org/10.1063/1.459472[Crossref]
  • [11] W. Auer:Kalorimetrische Zustandsgrössen, Landolt-Börnstein 6. Auflage, II Band, 4 Teil, Kl. A. Schäfer and E. Lax., Springer-Verlag, Berlin, 1961, p. 560.
  • [12] G.P. Johari, G. Fleissner, A. Hallbrucker and E. Mayer: “Thermodynamic Continuity between Gassy and Normal Water”,J. Phys. Chem., Vol. 98, (1994) pp. 4719–4725. http://dx.doi.org/10.1021/j100068a038[Crossref]
Typ dokumentu
Bibliografia
Identyfikatory
Identyfikator YADDA
bwmeta1.element.-psjd-doi-10_2478_BF02476509
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