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2005 | 3 | 1 | 157-168
Tytuł artykułu

Synthesis, characterization and structure of the Bis(methyl-cyclopentadienyl)vanadium(IV) carboxylates

Treść / Zawartość
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
The 1,1’-dimethylvanadocene dichloride ((C5H4CH3)2VCl2) reacts in aqueous solution with various carboxylic acids giving two different types of complexes. The 1,1’-dimethylvanadocene complexes of monocarboxylic acids (C5H4CH3)2V(OOCR)2 (R=H,CCl3, CF3, C6H5) contain two monodentate carboxylic ligands, whereas oxalic and malonic acids act as chelate compounds of the formula (C5H4CH3)2V(OOC-A-COO) (A=−, CH2). The structure of the (C5H4CH3)2 V(OOCCF3)2 complex was determined by single crystal X-ray diffraction analysis. The isotropic and anisotropic EPR spectra of all the complexes prepared were recorded. The obtained EPR parameter values were found to be in agreement with proposed structures.
Wydawca

Czasopismo
Rocznik
Tom
3
Numer
1
Strony
157-168
Opis fizyczny
Daty
wydano
2005-03-01
online
2005-03-01
Twórcy
  • The Department of General and Inorganic Chemistry, University of Pardubice, nám. Ĉs. legií 565, 532 10, Pardubice, Czech Republic, jaromir.vinklarek@upce.cz
  • The Department of General and Inorganic Chemistry, University of Pardubice, nám. Ĉs. legií 565, 532 10, Pardubice, Czech Republic
  • Department of Inorganic Chemistry, Charles University, Hlavova 2030, 128 40, Prague 2, Czech Republic
  • Research Centre “New Inorganic Compounds and Advanced Materials”, University of Pardubice, nám. Ĉs. legií 565, 532 10, Pardubice, Czech Republic
  • The Department of General and Inorganic Chemistry, University of Pardubice, nám. Ĉs. legií 565, 532 10, Pardubice, Czech Republic
Bibliografia
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Typ dokumentu
Bibliografia
Identyfikatory
Identyfikator YADDA
bwmeta1.element.-psjd-doi-10_2478_BF02476246
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