Czasopismo
Tytuł artykułu
Autorzy
Warianty tytułu
Języki publikacji
Abstrakty
The kinetics of the oxidation of five catecholamines viz., dopamine (A), L-dopa (B), methyldopa (C), epinephrine (D) and norepinephrine (E) by sodium N-chloro-p-toluenesulfonamide or chloramine-T (CAT) in presence of HClO4 was studied at 30±0.1 °C. The five reactions followed identical kinetics with a first-order dependence on [CAT]o, fractional-order in [substrate]o, and inverse fractional-order in [H+]. Under comparable experimental conditions, the rate of oxidation of catecholamines increases in the order D>E>A>B>C. The variation of ionic strength of the medium and the addition of p-toluenesulfonamide or halide ions had no significant effect on the reaction rate. The rate increased with decreasing dielectric constant of the medium. The solvent isotope effect was studied using D2O. A Michaelis-Menten type mechanism has been suggested to explain the results. Equilibrium and decomposition constants for CAT-catecholamine complexes have been evaluated. CH3C6H4SO2NHCl of the oxidant has been postulated as the reactive oxidizing species and oxidation products were identified. An isokinetic relationship is observed with β=361 K, indicating that enthalpy factors control the reaction rate. The mechanism proposed and the derived rate law are consistent with the observed kinetics.
Słowa kluczowe
Czasopismo
Rocznik
Tom
Numer
Strony
326-346
Opis fizyczny
Daty
wydano
2005-06-01
online
2005-06-01
Twórcy
autor
- Department of Post-Graduate Studies in Chemistry, Central College, Bangalore University, 560 001, Bangalore, India, pswamy_chem@yahoo.com
autor
- Department of Post-Graduate Studies in Chemistry, Central College, Bangalore University, 560 001, Bangalore, India
autor
- Department of Post-Graduate Studies in Chemistry, Central College, Bangalore University, 560 001, Bangalore, India
Bibliografia
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Typ dokumentu
Bibliografia
Identyfikatory
Identyfikator YADDA
bwmeta1.element.-psjd-doi-10_2478_BF02476000