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2004 | 2 | 4 | 698-708
Tytuł artykułu

Clusterization of water molecules as deduced from statistical mechanical approach

Treść / Zawartość
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Using the methods of statistical mechanics we have shown that a homogeneous water network is unstable and spontaneously disintegrates to the nonhomogeneous state (i.e. peculiar clusters), which can be treated as an ordinary state of liquid water. The major peculiarity of the concept is that it separates the paired potential into two independent components-the attractive potential and the repulsive one, which in turn should feature a very different dependence on the distance from the particle (a water molecule in the present case). We choose the interaction potential as a combination of the ionic crystal potential and the vibratory potential associated with the elastic properties of the water system as a whole. The number ℵ of water molecules that enters a cluster is calculated as a function of several parameters, such as the dielectric constant, the mass of a water molecule, the distance between nearest molecules, and the vibrations of nearest molecules in their nodes. The number of H2O molecules that comprise a cluster is estimated as about ℵ ≈ 900, which agrees with the available experimental data.
Słowa kluczowe
Wydawca

Czasopismo
Rocznik
Tom
2
Numer
4
Strony
698-708
Opis fizyczny
Daty
wydano
2004-12-01
online
2004-12-01
Twórcy
  • Institute of Physics, National Academy of Sciences, Prospect Nauky 46, UA-03028, Kyïv, Ukraine, krasnoh@iop.kiev.ua
Bibliografia
  • [1] V.I. Gaiduk and V.V. Gaiduk: “Simple molecular model of orientation relaxation of liquid water”, Russ. J. Phys. Chem, Vol. 71, (1997), pp. 1637–1642.
  • [2] C. Rønne, P.-O. Estrand and S.R. Keiding: “THz spectroscopy of liquid H2O and D2O”Phys. Rev. Lett, Vol. 82, (1999), pp. 2888–91. http://dx.doi.org/10.1103/PhysRevLett.82.2888[Crossref]
  • [3] V.D. Zelepukhin, I.D. Zelepukhin and V. Krasnoholovets: “Thermodynamic features and molecular organization of degassed aqueous system”Khimich. Fiz., Vol. 12, (1993), [in Russian; English translation:Sov. Jnl. Chem. Phys, Vol. 12, (1994), pp. 1461–84].
  • [4] A.V. Kondrachuk, V. Krasnoholovets, A.I. Ovcharenko and E.D. Chesnokov: “Determination of the water structuring by the pulsed NMR method”, Khimich. Fiz., Vol. 12, (1993), [in Russian; English translation:Sov. Jrn. Chem. Phys, Vol. 12, (1994), pp. 1485–92].
  • [5] V. Krasnoholovets, P. Tomchuk and L. Lukyanets: “Proton transfer and coherent phenomena in molecular structures with hydrogen bonds”, Adv. Chem. Phys., Vol. 125, (2003), pp.351–548.
  • [6] V.D. Zelepukhin and I.D. Zelepukhin:A clue to “living” water, Kaynar, Alma-Ata, 1987. [in Russian]
  • [7] T.H. Maugh II: “Soviet science: a wonderful water from Kazakhstan”, Science, Vol. 202 (1978), pp. 414. http://dx.doi.org/10.1126/science.202.4366.414[Crossref]
  • [8] G.P. Gordeev and T. Khaidarov: “Temperature dependence of dynamic parameters of water”, Water in biological systems and their components, Ser.: Molecular Physics and Biophysics of Waters Systems, Leningrad State University, Leningrad, (1983), pp. 3–9 [in Russian]
  • [9] W.A.P. Luck, Structure of water and aqueous solutions, Verlag Chemie, Weinheim, 1974.
  • [10] V. Krasnoholovets and B. Lev: “Systems of particles with interaction and the clusterformationin condensed matter”, Cond. Matt. Phys., Vol. 6, (2003), pp. 67–83. [alsohttp://arXiv.org/abs/cond-mat/0210131]
  • [11] C. Kittel:Introduction to solid state physics, Nauka, Moscow, 1978. [Russian translation]
  • [12] M. Bounias and V. Krasnoholovets: “Scanning the structure of ill-known spaces: Part 1. Founding principles about mathematical constitution of space”, Kybernetes: The Int. J. Systems and Cybernetics, Vol. 32 (2003), pp. 945–75. [alsohttp://arXiv.org/abs/physics/0211096] http://dx.doi.org/10.1108/03684920310483126[Crossref]
  • [13] M. Bounias and V. Krasnoholovets: “Scanning the structure of ill-known spaces: Part 2. Principles of construction of physical space”, ibid., Vol. 32, (2003), pp. 976–1004. [alsohttp://arXiv.org/abs/physics/0212004] http://dx.doi.org/10.1108/03684920310483135[Crossref]
  • [14] M. Bounias and V. Krasnoholovets: “Scanning the structure of ill-known spaces: Part 3. Distribution of topological structures at elementary and cosmic scales”, ibid., Vol. 32, (2003), pp. 1005–20. [alsohttp://arXiv.org/abs/physics/0301049] http://dx.doi.org/10.1108/03684920310483144[Crossref]
  • [15] V. Krasnoholovets and D. Ivanovsky: “Motion of a particle and the vacuum”, Phys. Essays, Vol. 6, (1993), pp. 554–63. [alsohttp://arXiv.org/abs/quant-ph/9910023] http://dx.doi.org/10.4006/1.3029092[Crossref]
  • [16] V. Krasnoholovets: “Motion of a relativistic particle and the vacuum”, Phys. Essays, Vol. 10, (1997), pp. 407–16. [alsohttp://arXiv.org/abs/quant-ph/9903077] [Crossref]
  • [17] V. Krasnoholovets: “On the nature of spin, inertia and gravity of a moving canonical particle”, Ind. J. Theor. Phys., Vol. 48, (2000), pp. 97–132. [alsohttp://arXiv.org/abs/quant-ph/0103110]
  • [18] V. Krasnoholovets: “Space structure and quantum mechanics”, Spacetime & Substance, Vol. 1, (2000), pp. 172–75. [alsohttp://arXiv.org/abs/quant-ph/0106106]
  • [19] V. Krasnoholovets: “Submicroscopic deterministic quantum mechanics”, Int. J. Comput. Anticip. Systems, Vol. 11, (2002), pp. 164–79. [alsohttp://arXiv.org/abs/quant-ph/0109012]
  • [20] V. Krasnoholovets and V. Byckov: “Real inertons against hypothetical gravitons. Experimental proof of the existence of inertons”, Ind. J. Theor. Phys., Vol. 48, (2000), pp. 1–23. [alsohttp://arXiv.org/abs/quant-ph/0007027]
  • [21] V. Krasnoholovets: “On the theory of the anomalous photoelectric effect stemming from a substructure of matter waves”, Ind. J. Theor. Phys., Vol. 49, (2001)pp. 1–32. [alsohttp://arXiv.org/abs/quant-ph/9906091]
  • [22] V. Krasnoholovets: “Gravitation as deduced from submicroscopic quantum mechanics”, submitted toFizika B. [alsohttp://arXiv.org/abs/hep-th/0205196]
  • [23] J.M. Ziman:Elemnts of advanced quantum theory, Mir, Moscow, 1971. [Russian translation from the edition: Cambridge, at the University Press, 1969]
  • [24] H. Haken:Quantum field theory of solids, Nauka, Moscow, 1980. [Russian traslation from German:Quantenfeldtheorie des Festköpers; B.G. Teubner, Stuttgart, 1973; Chapters 2 and 3]
  • [25] A.S. Davydov:The theory of solid, Nauka, Moscow, 1976. [in Russian]
  • [26] H. Stobbe and G. Peschel: “Experimental determination of the static permittivity of extremely thin liquid layers of water dependent on their thickness”, Colloid. Polym. Sci., Vol. 275, (1997), pp. 162–69. http://dx.doi.org/10.1007/s003960050066[Crossref]
  • [27] M. Chaplin:Water structure, http://www.sbu.ac.uk/water.
  • [28] I. Smirnov: “Activated Water”, Electronic J. Biotechnology, Vol. 6, (2003), http://www.bioline.org.br/request?ej03016.
Typ dokumentu
Bibliografia
Identyfikatory
Identyfikator YADDA
bwmeta1.element.-psjd-doi-10_2478_BF02475570
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