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Catalytic Supramolecular Photochirogenesis

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Supramolecular photochirogenesis is a new strategy for circumventing the inherent difficulties encountered in conventional photochirogenesis, i.e. the interactions associated with geometrically less-defined, short-lived excited states, by confining a prochiral substrate(s) in a chiral supramolecular environment(s) prior to photoexcitation. This rather simple, but very successful, strategy has been applied to a variety of chiral photoreactions. However, a stoichiometric, or even excess amount of supramolecular host is often needed to ensure full complexation of the substrate, and achieve the optimum stereochemical outcome. This apparent drawback has recently been removed by introducing a sensitizing moiety to the supramolecular host, or by bathochromically shifting the absorption band of substrate through Lewis acid, or charge-transfer complexation. Recent progress in catalytic supramolecular photochirogenesis will be reviewed.

Opis fizyczny
  • Key Laboratory of Green
    Chemistry & Technology of Ministry of Education, College of Chemistry
    and State Key Laboratory of Biotherapy, West China Medical
    School, Sichuan University, 29 Wangjiang Road, Chengdu 610064,
  • Key Laboratory of Green
    Chemistry & Technology of Ministry of Education, College of Chemistry
    and State Key Laboratory of Biotherapy, West China Medical
    School, Sichuan University, 29 Wangjiang Road, Chengdu 610064,
  • Key Laboratory of Green
    Chemistry & Technology of Ministry of Education, College of Chemistry
    and State Key Laboratory of Biotherapy, West China Medical
    School, Sichuan University, 29 Wangjiang Road, Chengdu 610064,
  • Department of Applied
    Chemistry, Osaka University, 2-1 Yamada-oka, Suita 565-0871,
  • ---
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