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Tytuł artykułu

Acid-Catalyzed Dehydration of Fructose to 5-(Hydroxymethyl)furfural

Treść / Zawartość
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Hydroxymethylfurfural (abbreviated as HMF), also 5-(hydroxymethyl)furfural, is an organic compound derived from dehydration of certain sugars. HMF is primarily considered as a starting material for liquid transportation fuels and polyester building block chemicals. The most convenient synthetic method of HMF is based on acidcatalyzed triple dehydration of fructose. Although there are many studies about fructose dehydration to 5-HMF since this field started to be investigated, it is necessary to provide a new review about fructose dehydration to 5-HMF. In the following, we will make a summary (in detail) of catalytic systems of fructose dehydration to HMF achieved by different acid catalysts, including mineral and organic acids, metal complexes, heteropoly acid-based materials, Ionic Liquids, ion-exchange resins, zeolites, functionalized carbonaceous materials and mesoporous silica materials. It has been demonstrated that nearly full conversion of fructose and 100% HMF selectivity could be obtained with some acidic catalytic systems up to now.
Wydawca

Rocznik
Tom
2
Numer
1
Opis fizyczny
Daty
otrzymano
2014-11-27
zaakceptowano
2015-03-24
online
2015-05-29
Twórcy
  • Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, D-45470 Mülheim an der Ruhr, Germany
  • Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, D-45470 Mülheim an der Ruhr, Germany
autor
  • Key Laboratory for Advanced Material, Research Institute of Industrial Catalysis, East China University of Science and Technology, 130 Meilong Road, Shanghai
    200237 (P. R. China
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