Characterization of vanadia catalysts on structured micro-fibrous glass supports for selective oxidation of hydrogen sulfide

• Autorzy: Tatyana V. Larina , Svetlana V. Cherepanova , Nina A. Rudina , Boris A. Kolesov , Andrey N. Zagoruiko
• Języki publikacji: EN

Abstrakty

EN

This work is focused on the characterization of a novel vanadium pentoxide catalysts on a glass-fiber support. The catalyst support consists of a non-porous glass-fiber fabric covered with an additional external surface layer of porous secondary support of SiO2. The vanadia active component is synthesized from vanadyl oxalate precursor by means of an impulse surface thermo-synthesis method. Such catalysts demonstrate high activity and appropriate selectivity in the reaction of H2S oxidation by oxygen into sulfur in the practically important temperature range below 200°C. According to the characterization data, the freshly prepared vanadia catalyst partially consists of mostly the amorphous and badly ordered vanadia with some part of the wellcrystallized V2O5 phase. Under the reaction conditions the main part of vanadia in the catalyst remains in the amorphous V2O5 form, while the less part becomes reduces into of VO2 and other vanadium oxides (such as VO, V2O3 V3O7 and V4O9). Most probably, the crystallized V2O5 in course of reaction is responsible for the deep oxidation of hydrogen sulphide into SO2, while the lower vanadium oxides promote the selective H2S oxidation into elemental sulfur.

Słowa kluczowe

EN

Hydrogen sulfide; oxidation; sulfur; vanadia; glass fibers

• Czasopismo: Catalysis for Sustainable Energy
• Rocznik: 2014
• Tom: 2
• Numer: 1

Daty

otrzymano

2015-10-24

zaakceptowano

2015-11-03

online

2016-02-02

Twórcy

autor

Tatyana V. Larina

• Boreskov Institute
  of Catalysis, prospekt Lavrentieva 5, Novosibirsk, 630090, Russia

autor

Svetlana V. Cherepanova

• Boreskov Institute
  of Catalysis, prospekt Lavrentieva 5, Novosibirsk, 630090, Russia
• Novosibirsk
  Technical State University, prospekt K.Marksa, Novosibirsk, 630073,
  Russia

autor

Nina A. Rudina

• Boreskov Institute
  of Catalysis, prospekt Lavrentieva 5, Novosibirsk, 630090, Russia

autor

Boris A. Kolesov

• Institute of Inorganic Chemistry, SB RAS, pr.
  Lavrentieva, 3, Novosibirsk, 630090, Russia

autor

Andrey N. Zagoruiko

• Novosibirsk
  Technical State University, prospekt K.Marksa, Novosibirsk, 630073,
  Russia
• Tomsk Polytechnic University, prospekt Lenina,
  30, Tomsk, 634050, Russia
• Research and Educational Center for Energy
  Efficient Catalysis, Novosibirsk State University, Pirogova Str. 2,
  Novosibirsk, 630090, Russia

Bibliografia

• [1] Piéplu A., Saur O., Lavalley J.C., Legendre O., Nédez C., Clauscatalysis and H2S selective oxidation. Catal. Rev., Sci. Eng.1998, 40, 409-450.
• [2] Wieckowska J., Catalytic and adsorptive desulphurization ofgases. Catal. Today, 1995, 24, 405-465.
• [3] Zagoruiko A.N., Shinkarev V.V., Vanag S.V., Bukhtiyarova G.A.,Catalytic processes and catalysts for production of elementalsulfur from sulfur-containing gases. Catalysis in Industry, 2010,4, 343-352.
• [4] Lagas J.A., Borsboom J., Heijkoop G., Claus process gets extraboost. Hydrocarbon Proc., 1989, 68, 40-42.
• [5] van Nisselrooy P.F.M.T., Lagas J.A., Superclaus reduces SO2emission by the use of a new selective oxidation catalyst.Catal. Today, 1993, 16, 263-271.
• [6] Marshneva V.I., Mokrinskii V.V., Catalytic activity of metaloxides in hydrogen sulfide oxidation by oxygen and sulfurdioxide. Kinet. Catal., 1988, 29, 989-993.
• [7] Davydov A.A., Marshneva V.I., Shepotko M.L., Metal oxides inhydrogen sulfide oxidation by oxygen and sulfur dioxide: I.The comparison study of the catalytic activity. Mechanism ofthe interactions between H2S and SO2 on some oxides. AppliedCatal. A, Gen., 2003, 244, 93-100.
• [8] Kalinkin P., Kovalenko O., Lapina O., Khabibulin D., Kundo N.,Kinetic peculiarities in the low-temperature oxidation of H2Sover vanadium catalysts. J. Mol. Catal. A, Chem., 2002, 178,173-180.
• [9] León M., Jiménez-Jiménez J., Jiménez-López A., Rodríguez-Castellón E., Soriano D., López Nieto J.M., Vanadiumoxide-porous phosphate heterostructure catalysts for theselective oxidation of H2S to sulphur. Solid State Sci., 2010, 2,996-1001.[Crossref][WoS]
• [10] Palma V., Barba D., Low temperature catalytic oxidation of H2Sover V2O5/CeO2 catalysts. Int. J. Hydrogen Energy, 2014, 39,21524–21530.
• [11] Bineesh V.K., Kim M.I., Lee G.H., Selvaraj M., Park D.W.,Catalytic performance of vanadia-doped alumina-pillared clayfor selective oxidation of H2S. Appl. Clay Sci., 2013, 74, 127-134.
• [12] Kim M.I., Park D.W., Park S.W., Yang X., Choi J.S., Suh D.J.,Selective oxidation of hydrogen sulfide containing excesswater and ammonia over vanadia–titania aerogel catalysts.Catal. Today, 2006, 111, 212-216.
• [13] Yasyerli S., Dogu G., Dogu T., Selective oxidation of H2S toelemental sulfur over Ce–V mixed oxide and CeO2 catalystsprepared by the complexation. Catal. Today, 2006, 117,271-278.
• [14] Soriano M.D., Lopez Nieto J.M., Ivars F., Concepcion P.,Rodriguez-Castellon E., Alkali-promoted V2O5 catalysts for thepartial oxidation of H2S to sulphur. Catal. Today, 2012, 192,28-35.
• [15] Balzhinimaev B.S., Paukshtis E.A., Vanag S.V., Suknev A.P.,Zagoruiko A.N., Glass-fiber catalysts: Novel oxidation catalysts,catalytic technologies for environmental protection. Catal.Today, 2010, 151, 195-199.[WoS]
• [16] Zagoruiko A.N., Vanag S.V., Balzhinimaev B.S., PaukshtisE.A., Simonova L.G., Zykov A.M., Anichkov S.N., Hutson N.D.,Catalytic flue gas conditioning in electrostatic precipitators ofcoal-fired powerplants. Chem. Eng. J., 2009, 154, 325-332.[WoS]
• [17] Zagoruiko A.N., Balzhinimaev B.S., Vanag S.V., Goncharov V.B.,Lopatin SA, Zykov A.M., Anichkov S.N., Zhukov Y.N., YankilevichV.M., Proskokov N.N., Hutson N.D., Novel catalytic process forflue gas conditioning in electrostatic precipitators of coal-firedpower plants. J. Air Waste Manag. Assoc., 2010, 60, 1002-1008.[WoS]
• [18] Zagoruiko A.N., Lopatin S.A., Bal’zhinimaev B.S., Gil’mutdinovN.R., Sibagatullin G.G., Pogrebtsov V.P., Nazmieva I.F., Theprocess for catalytic incineration of waste gas on IC-12-S102platinum glass fiber catalyst. Catalysis in Industry, 2010, 2,113-117.
• [19] Zagoruiko A.N., Vanag S.V., Reverse‐flow reactor concept forcombined SO2 and CO oxidation in smelter off‐gases. Chem.Eng. J., 2014, 238, 86-62.
• [20] Vanag S.V., Paukshtis E.A., Zagoruiko A.N., Properties ofplatinum-containing glass-fiber catalysts in the SO2 oxidationreaction. Reaction Kinetics, Mechanisms and Catalysis, 2015,116, 147-158.
• [21] Matatov-Meytal Y., Sheintuch M., Catalytic fibers and cloths.Appl. Catal. A, Gen., 2002, 231, 1-16.
• [22] Reichelt E., Heddrich M.P., Jahn M., Michaelis A., Fiber basedstructured materials for catalytic applications. Appl Catal. A,Gen., 2014, 476, 78-90.
• [23] Russian Patent for Utility model No 101652, 2010.
• [24] Russian Patent for Utility model No 145037, 2014.
• [25] Lopatin S.A., Zagoruiko A.N., Pressure drop of structuredcartridges with fiber‐glass catalysts. Chem. Eng. J., 2014, 238,31-36.[WoS]
• [26] Lopatin S.A., Mikenin P.E, Pisarev D.A., Baranov D.V.,Zazhigalov S.V., Zagoruiko A.N., Pressure drop and masstransfer in the structured cartridges with fiber-glass catalyst.Chem. Eng. J., 2015, 282, 58-65.
• [27] Mikenin P.E., Tsyrul’nikov P.G., Kotolevich Y.S., Zagoruiko A.N.,Vanadium Oxide Catalysts on Structured Microfiber Supportsfor the Selective Oxidation of Hydrogen Sulfide. Catalysis inIndustry, 2015, 2, 155-160.
• [28] Kotolevich Y.S., Suprun E.A., Sharafutdinov M.R., Tsyrul’nikovP.G., Salanov A.N., Goncharov V.B., Influence of the fueladditive on the characteristics of silver catalysts producedby IST method at the glass-fiber supports. Russian PhysicsJournal, 2011, 12, 48-53.
• [29] Afonasenko T.N., Tsyrul’nikov P.G., Gulyaeva T.I., Leont’evaN.N., Smirnova N.S., Kochubei D.I., Mironenko O.O.,Svintsitskii D.A., Boronin A.I., Kotolevich Y.S., Suprun E.A.,Salanov A.N., (CuO-CeO2)/glass cloth catalysts for selectiveCO oxidation in the presence of H2: The effect of the natureof the fuel component used in their surface self-propagatinghigh-temperature synthesis on their properties. Kinet. Catal.,2013, 54, 59-68.
• [30] Mironenko O.O., Shitova N.B., Kotolevich Y.S., SharafutdinovM.R., Struikhina N.O., Smirnova N.S., Kochubey D.I., ProtasovaO.V., Trenikhin M.V., Stonkus O.A., Zaikovskii V.I., GoncharovV.B., Tsyrul’nikov P.G., Pd/fiber glass and Pd/5% γ-Al2O3/fiberglass catalysts by surface self-propagating thermal synthesis.International Journal of Self-Propagating High-TemperatureSynthesis, 2012, 21, 139-145.
• [31] Kotolevich Y.S., Khramov E.V., Mironenko O.O., ZubavichusYa.V., Murzin V.Yu., Frey D.I., Metelev S.E., Shitova N.B.,Tsyrulnikov P.G., Supported Palladium Catalysts Prepared bySurface Self-Propagating Thermal Synthesis. InternationalJournal of Self-Propagating High-Temperature Synthesis, 2014,23, 9-17.
• [32] Desyatikh I.V., Vedyagin A.A., Kotolevich Y.S., Tsyrul’nikov P.G.,Preparation of СuО - СeО2 catalysts deposited on glass clothby surface self-propagating thermosynthesis method (SST).Combustion Explosion and Shock Waves, 2011, 47, 677-682.
• [33] Russian Patent No 2 455 067, 2012.
• [34] Russian Patent No 2 549 906, 2015.
• [35] Darling R.B., Iwanaga S., Structure, properties, and MEMS andmicroelectronic applications of vanadium oxides. Sadhana,2009, 34, 531-542.[WoS][Crossref]
• [36] Ilyina E.V., Mishakov I.V., Vedyagin A.A., Cherepanova S.V.,Nadeev A.N., Bedilo A.F., Klabunde K.J., Synthesis and characterizationof mesoporous VOx/MgO aerogels with high surfacearea // Microporous. Microporous and Mesoporous Materials,2012, 160, 32-40.
• [37] Cherepanova S.V., Tsybulya S.V., Simulation of X-ray powderdiffraction patterns for low-
• [ordered materials. J. Mol. Catal., 2000, 158, 263-266.
• [38] Catana G., Rao R.R., Weckhuysen B.M., Voort P.V.D., Vansant E.,Schoonheydt R.A., J. Phys. Chem. B., 1998, 102, 8005-8012.
• [39] Liu Y.M., Feng W.L., Li T.Ch., He H.Y., Dai W.L., Huang W., Cao Y.,Fan K.N., J. Catal., 2006, 239, 125-136.
• [40] El-Korso S., Rekkab I., Choukchou-Braham A., Bedrane S.,Pirault-Roy L., Kappenstein C., Bull. Mater. Sci., 2012, 35,1187-1194.
• [41] Ilinskiy A.V., Kvashenkina O.E., Shadrin E.B., Semiconductors,2012, 46, 422-429.
• [42] Khodakov A., Olthof B., Bell A.T., Iglesia E., Structure andcatalytic properties of supported vanadium oxides: supporteffects on oxidative dehydrogenation reactions. J. Catal., 1999,181, 205-216.
• [43] Argyle M.D., Chen K., Bell A.T., Iglesia E., E.Iglesia Effect ofcatalyst Structure on Dehydrogenation of Ethane and Propaneon Alumina-Supported Vanadia. J. Catal., 2002, 208, 139-149.
• [44] Bachman H.G., Achmed F.R., Barnes W.H., The crystal structureof vanadium pentoxide. Z.Kristallogr., 1961, 115, 110-131.
• [45] Shklover V., Haibach T., Ried F., Nesper R., Crystal structureof the product of Mg(2+) insertion into V2O5 single crystals. J.Solid State Chem., 1996, 123, 317-323.
• [46] Wei J., Ji H., Guo W., Nevidomskyy A.H., Natelson D., Hydrogenstabilization of metallic vanadium dioxide in single-crystalnanobeams. Nature Nanotech Lett., 2012, 7, 357-362.

Identyfikatory

DOI

10.1515/cse-2015-0007