Use of Natural Nanotubes of Halloysite Clay for Thermochemical Conversion of Cottonseed Oil

• Autorzy: T.A. Mammadova , N.V. Hasankhanova , Kh.Sh. Teyubov , E.N. Askerova , T.S. Latifova , V.M. Abbasov
• Języki publikacji: EN

Abstrakty

EN

The process of obtaining low molecular weight C2-C4 olefins, as a result of thermal and thermocatalytic conversion of cottonseed oil was investigated. The total content of olefin gases obtained by the thermal conversion of cottonseed oil in the temperature range of 700-800°C is 57.2-65.2 wt. %. Thermocatalytic conversion of cottonseed oil on the natural halloysite nanotubes as a catalyst in the temperature range of 500-800 ° provides the total content of olefins 10.8-69.2 wt. with increased yield of propylene and butenes.

Słowa kluczowe

EN

thermal and thermocatalytic cracking; halloysite; vegetable oil; low molecular weight olefins

• Czasopismo: Catalysis for Sustainable Energy
• Rocznik: 2014
• Tom: 2
• Numer: 1

Daty

otrzymano

2014-11-14

zaakceptowano

2014-12-29

online

2015-01-18

Twórcy

autor

T.A. Mammadova

• Y.H. Mammadaliyev name Institute of Petrochemical
  Processes. ANAS, Baku Az1025, Baku Ave Khojaly 30

autor

N.V. Hasankhanova

• Y.H. Mammadaliyev name Institute of Petrochemical
  Processes. ANAS, Baku Az1025, Baku Ave Khojaly 30

autor

Kh.Sh. Teyubov

• Y.H. Mammadaliyev name Institute of Petrochemical
  Processes. ANAS, Baku Az1025, Baku Ave Khojaly 30

autor

E.N. Askerova

• Y.H. Mammadaliyev name Institute of Petrochemical
  Processes. ANAS, Baku Az1025, Baku Ave Khojaly 30

autor

T.S. Latifova

• Y.H. Mammadaliyev name Institute of Petrochemical
  Processes. ANAS, Baku Az1025, Baku Ave Khojaly 30

autor

V.M. Abbasov

• Y.H. Mammadaliyev name Institute of Petrochemical
  Processes. ANAS, Baku Az1025, Baku Ave Khojaly 30

Bibliografia

• [1] Bridgwater A.V., Peacocke, G.V.C., Fast pyrolysis processes forbiomass, Sust. Energy Rev., 2000, 4 (1), 1-73.[Crossref]
• [2] Suarez P.A., Meneghetti S.M., Meneghetti M.R., Wolf C.R.,Transformation of triglycerides into fuels, polymers andchemicals: some applications of catalysis in oleochemistry ,Quim Nova, 2007, 30, 667-676.[WoS][Crossref]
• [3] Alencar J.W., Alves P.B., Craveiro A.A., Pyrolysis of tropicalvegetable oils, Journal of Agricultural and Food Chemistry,1983,31 (6), 1268-1276.[Crossref]
• [4] Fortes I.C., Baugh P.J ., Pyrolysis -GC/MS studies of vegetableoils from macauba fruit, J.Anal. Appl. Pyrolysis, 1994,72,103-111.
• [5] Fortes I.C., Baugh P.J., Study of analytical on-line pyrolysis ofoils from macauba fruit, J. Braz. Chem. Soc., 1996, 10, 469-477.
• [6] Park K.C., Ihm S.K., Comparison of Pt/Zeolite Catalysts forn-Hexadecane Hydroisomerization, Appl. Catal., A: GeneralAppl. Catal., 2000, 203, 201-207.
• [7] Katikaneni S.P.R., Adjaye J.D., Bakhshi N.N., Catalyticconversion of canola oil to fuels and chemicals over variouscracking catalysts, Can. J. Chem. Eng., 1995, 73. 484-497.
• [8] Schwab A.W., Dykstra G.J., Selke E., Sorenson S.C., Pryde E.H.,Diesel fuel from thermal-decomposition of soybean oil, J. AmOil Chem Soc., 1988, 65, 1781-1786.
• [9] Santos F.R., Ferreira J.C., Costa S.R., Catalytic decompositionof soybean oil in the presence of different zeolites, Quim Nova,1998, 21, 560-563.[Crossref]
• [10] Idem R.O., Katikaneni S.P., Bakhshi N.N., Thermal cracking ofcanola oil: reaction products in the presence and absence ofsteam, Energy Fuels, 1996, 10, 1150-1162.[Crossref]
• [11] Idem R.O., Katikaneni S.P., Bakhshi N.N., Catalytic conversionof canola oil to fuels and chemicals: roles of catalyst acidity,basicity and shape selectivity on product distribution, FuelProcess Tech., 1997, 51, 101-125.
• [12] Katikaneni S.P., Bakhshi N.N., Adjaye J.D., Studies on thecatalytic conversion of canola oil to hydrocarbons: influence ofhybrid catalysts and steam, Energy Fuels, 1995, 9, 599-609.[Crossref]
• [13] Katikaneni S.P., Adjaye J.D., Idem R.O., Bakhshi N.N.,Performance studies of various cracking catalysts in theconversion of canola oil to fuels and chemicals in a fluidizedbedreactor, J. Am Oil Chem. Soc.,1998, 75, 381-391
• [14] Prasad Y.S., Bakhshi N.N., Mathews J.F., Eager R.L. Catalyticconversion of canola oil to fuels and chemical feedstocks, 1.Effect of process conditions on the performance of HZSM-5catalyst, Can. J. Chem. Eng., 1986, 64, 278-284.
• [15] Twaiq F.A., Zabidi N.A., Biores B.S., Catalytic conversion ofpalm oil to hydrocarbons; performance of various zeolitecatalysts, Ind. Eng. Chem. Res., 1999, 38, 3230-3237.
• [16] Sharma R.K., Bakhshi N.N., Catalytic upgrading of biomassderived oils to transportation fuels and chemicals, Can J. Chem.Eng., 1991, 69, 1071-1081.
• [17] Nawar W.W., Termal degradation of lipids – review, J. Agric.Food Chem., 1989, 17, 18-24.[Crossref]
• [18] Elordi G, Olazar M., Lopez G., Castano P., J. Bilbao J., Role ofpore structure in the deactivation of zeolites (HZSM-5, Hpand HY) by coke in the pyrolysis of polyethylene in a conicalspouted bed reactor, Appl. Catal. B., Env., 2011, 102, 224-231.[WoS]
• [19] Donk S.V., Janssen A.H, J.H. Bitter, J.H. DeJong K.P., Generation,characterization and impact of mesopores in zeolite catalysts,Catal. Rev. Sci. Eng., 2003, 45, 297-319.
• [20] Carati G.A., Rizzoand C.N., Millini R.P., New trends in thesynthesis of crystalline microporous materials, Catal. Sci.Technol., 2013, 3, 833-857.[WoS]
• [21] Abdullayev E., Lvov Y., Halloysite clay nanotubes as aceramic “skeleton” for functional biopolymer compositeswith sustained drug release, J. Materials Chem. B., 2013, 1,2894-2903.[WoS]
• [22] Bergaya F., Theng B.K.G. , Lagaly G., Handbook of Clay Science,ed. Developments in Clay Science, Elsevier Ltd., 2006
• [23] Wilson L., Special clays from attapulgite to sepolite, IndustrialMinerals, 2004, 446, 54-61.
• [24] Joussein E., Petit S., Churchman J., Theng B., Righi D., DelvauxB., Halloysite clay minerals – A review, Clay Minerals, 2005, 40,383–426
• [25] Du M., Guo B., Jia D., Newly emerging applications of halloysitenanotubes: A review, Polymer International, 2010, 59, 574–582.[WoS]

Identyfikatory

DOI

10.1515/cse-2015-0001