Chitosan immobilization to the polypropylene nonwoven after activation in atmospheric – pressure nitrogen plasma

• Autorzy: Ľudmila Černáková , Mirko Černák , András Tóth , Mária Mikulášová , Monika Tomašková , Dušan Kováčik
• Języki publikacji: EN

Abstrakty

EN

Atmospheric-pressure air and nitrogen plasmas generated by surface dielectric barrier discharges have been used to incorporate new functionalities at the surface of polypropylene nonwoven fabric. The main goals were to activate the polymer surfaces for subsequent immobilization of chitosan from water solution without using any crosslinking and wetting agents. The samples were analyzed by diffuse reflectance infrared Fourier transform spectroscopy, scanning electron microscopy, and X-ray photoelectron spectroscopy. The nitrogen plasma treatment resulted in relatively high oxygen incorporation, about 9 atomic % mainly in aliphatic C=O type bonds and about 4 at.% of nitrogen incorporation in amine and other nitrogen functionalities. Chitosan was immobilized on the fabric fibers surfaces very homogeneously in amount of 2 - 5 g m-2. The chitosan coated samples exhibited a good laundering durability and strong antimicrobial activity against Bacillus subtilis and Escherichia coli.

EN

Słowa kluczowe

EN

chitosan; immobilization; atmospheric pressure plasma; polypropylene

• Czasopismo: Open Chemistry
• Rocznik: 2015
• Tom: 13
• Numer: 1

Daty

otrzymano

2014-01-31

zaakceptowano

2014-05-07

online

2014-12-01

Twórcy

autor

Ľudmila Černáková

• Slovak University of Technology, Faculty of Chemical and Food Technology, Institute of Polymer Materials, 812 37 Bratislava, Slovakia

autor

Mirko Černák

• Comenius University, Faculty of Mathematics, Physics and Informatics, Department of Experimental Physics, 842 48 Bratislava, Slovakia

autor

András Tóth

• Institute of Materials and Environmental Chemistry, Chemical Research Center, Hungarian Academy of Sciences, H-1025 Budapest, Hungary

autor

Mária Mikulášová

• Comenius University, Faculty of Natural Sciences, 842 15 Bratislava, Slovakia

autor

Monika Tomašková

• Slovak University of Technology, Faculty of Chemical and Food Technology, Institute of Polymer Materials, 812 37 Bratislava, Slovakia

autor

Dušan Kováčik

• Comenius University, Faculty of Mathematics, Physics and Informatics, Department of Experimental Physics, 842 48 Bratislava, Slovakia

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Identyfikatory

DOI

10.1515/chem-2015-0055