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2015 | 13 | 1 |
Tytuł artykułu

Catalytic activity of hexagonal MoO3modified with silver, palladium and copper

Treść / Zawartość
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Catalytic activity of solvothermally-synthesized hexagonal molybdenum trioxide (h-MoO3) in epoxidation of 1-octene by tert-butyl hydroperoxide and the effect of deposition of metal (Ag, Pd, Cu) nanoparticles on the properties of catalyst have been investigated. It has been shown that silver-modified MoO3 demonstrates the highest catalytic activity and selectivity in the reaction of 1,2-epoxyoctane formation, whereas MoO3 modified with Pd nanoparticles exhibits worse catalytic performance than bare MoO3; by contrast, copper-modified MoO3 does not catalyze the epoxidation reaction. The Ag/MoO3 catalyst was also found to be active in the reaction of 1-octene oxidation by molecular oxygen at the initial stage of the oxidation process.
EN
Wydawca
Czasopismo
Rocznik
Tom
13
Numer
1
Opis fizyczny
Daty
otrzymano
2013-11-23
zaakceptowano
2014-06-26
online
2014-11-01
Twórcy
  • Institute of Chemistry and Chemical Technologies, Lviv Polytechnic National University, 79013 Lviv, Ukraine
  • Institute of Chemistry and Chemical Technologies, Lviv Polytechnic National University, 79013 Lviv, Ukraine
  • Institute of Chemistry and Chemical Technologies, Lviv Polytechnic National University, 79013 Lviv, Ukraine
  • Department of Chemistry, Belarusian State University, 220030 Minsk, Belarus
  • Department of Chemistry, Belarusian State University, 220030 Minsk, Belarus
Bibliografia
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Typ dokumentu
Bibliografia
Identyfikatory
Identyfikator YADDA
bwmeta1.element.-psjd-doi-10_1515_chem-2015-0036
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