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Tytuł artykułu

New feats of alkene and alkyne asymmetric hydroamination catalyzed by copper and rhodium hydrides

Treść / Zawartość
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Hydroamination of unsaturated carbon-carbon bonds is a useful C-N bond forming reaction as it leads to products (amines, imines, enamines) of high synthetic value. While the hydroamination of terminal alkenes and alkynes under metal catalysis has been widely developed, the corresponding reactions with internal substrates remain a challenge. Two recent studies by Buchwald and by Dong which focus on enantioselective hydroamination of internal alkenes and alkynes respectively are of significant importance. [43,44] The results reported broaden the scope of hydroamination as a useful C-N bond forming process and allow acess to chiral amines which are difficult to synthesize by other methods.
Słowa kluczowe
Wydawca

Rocznik
Tom
2
Numer
1
Opis fizyczny
Daty
otrzymano
2015-10-13
zaakceptowano
2015-11-10
online
2016-02-03
Twórcy
  • Interdisciplinary
    Center for the Study of Inflammation, University of Ferrara, Via L.
    Borsari 46, I-44121 Ferrara (Italy)
Bibliografia
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  • [30].
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Typ dokumentu
Bibliografia
Identyfikatory
Identyfikator YADDA
bwmeta1.element.-psjd-doi-10_1515_asorg-2015-0006
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