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http://yadda.icm.edu.pl:80/baztech/element/bwmeta1.element.baztech-d387292d-2683-4f74-9893-4f07b6262aa5

Czasopismo

Materials Science Poland

Tytuł artykułu

Photocrosslinkable polymer based on 4-(3-(2,4-dichlorophenyl)-3-oxoprop-1-enyl) phenylacrylate: synthesis, reactivity ratio, and crosslinking studies

Autorzy Suresh, J.  Karthik, S.  Arun, A. 
Treść / Zawartość http://www.materialsscience.pwr.wroc.pl/
Warianty tytułu
Języki publikacji EN
Abstrakty
EN The acrylate monomer was synthesized by two step process. 2,4-dichloro-1-ene(4-hydroxyphenyl)phenone (DHP) was synthesized using 4-hydroxy benzaldehyde and 2,4-dichloro acetophenone. 4-[3-(2,4-dichloro-phenyl)3-oxoprop-1-en-1-yl]phenylacrylate (DCP) was prepared by reacting DHP with acryloyl chloride. The synthesized monomer was copolymerized with 2-hydroxyethyl acrylate and styrene using solution polymerization technique. Monomer and polymers were characterized by IR, NMR and UV techniques. The average molecular weight of the polymer was around 4000 g/mol. First and second decomposition temperature of the polymers was around 320 °C and 430 °C, respectively. The reactivity ratio of the polymers was calculated by Fineman-Ross, Kelen-Tudos and extended Kelen-Tudos methods. The synthesized monomer has been less reactive than the commercial monomer. The rate of photocrosslinking increased from 39 % to 99 % due to the using of copolymerization technique.
Słowa kluczowe
EN chalcone   acrylate   reactivity ratio   photocrosslinking   copolymer  
Wydawca Springer
Czasopismo Materials Science Poland
Rocznik 2016
Tom Vol. 34, No. 4
Strony 834--844
Opis fizyczny Bibliogr. 25 poz., rys., tab.
Twórcy
autor Suresh, J.
  • PG & Research Department of Chemistry, Government Arts College, Thiruvannamalai-606603. Tamilnadu, India.
autor Karthik, S.
  • PG & Research Department of Chemistry, Government Arts College, Thiruvannamalai-606603. Tamilnadu, India.
autor Arun, A.
  • PG & Research Department of Chemistry, Government Arts College, Thiruvannamalai-606603. Tamilnadu, India., aruna2075@yahoo.co.in
Bibliografia
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Uwagi
Opracowanie ze środków MNiSW w ramach umowy 812/P-DUN/2016 na działalność upowszechniającą naukę (zadania 2017).
Kolekcja BazTech
Identyfikator YADDA bwmeta1.element.baztech-d387292d-2683-4f74-9893-4f07b6262aa5
Identyfikatory
DOI 10.1515/msp-2016-0117