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Elektronika : konstrukcje, technologie, zastosowania

Tytuł artykułu

Photovoltaic bulk heterojunctions with interpenetrating network based on semiconducting polymers

Autorzy Modzelewski, M.  Klugmann-Radziemska, E. 
Treść / Zawartość
Warianty tytułu
Konferencja Proceedings of the European Summer School of Photovoltaics (04-07.07.2012 ; Kraków, Poland)
Języki publikacji EN
EN Poly(indenefluorene) belongs to the exotic and rare group of synthetic, photoactive, macromolecular compounds which may replace crystalline silicon in electronics in the future. Although the attempt of performance improvement it is highly probable that PIF itself is characterized by low exciton diffusion length and therefore (apart from PCBM and TCNQ) application of other electronacceptor in blends with that polymer may be pointless. There is a particular need of application other conjugated polymers with optimized band gap around 1.5 eV. Polymers with lower values of band gap may not deliver satisfying voltages even though they have well absorption properties. The main obstacle in commercial applications of low-band gap polymer based devices is that they have low values of operating currents and external quantum efficiencies. Few available examples of photovoltaic devices based of that kind of polymers manufactured in [3, 4] have EQEs less than 0,01%. New bulks based on other macromolecular chromophores are needed as presented devices based on PIF may be used only as a photonic detector of radiation.
Słowa kluczowe
PL fotowoltaika   polimery  
EN photovoltaic   polymers  
Wydawca Wydawnictwo SIGMA-NOT
Czasopismo Elektronika : konstrukcje, technologie, zastosowania
Rocznik 2012
Tom Vol. 53, nr 6
Strony 122--125
Opis fizyczny Bibliogr. 4 poz., rys., tab., wykr.
autor Modzelewski, M.
autor Klugmann-Radziemska, E.
  • Gdańsk University of Technology, Chemical Faculty
[1] Koster L. J. A., V. D. Mihailetchi, P. W. M. Blom: Ultimate efficiency of polymer/fullerene bulk heterojunction solar cells, Appl. Phys. Lett. 88, 093511 (2006).
[2] Reisch H., Wiesler U., Seherf U., Tuytuylkov N.: Poly(indenofluorene) (PIF), a Novel Low Band Gap Polyhydrocarbon, Macromolecules, 29 (1996).
[3] Bundgaard E., Krebs F. C.: Low band gap polymers for organic photovoltaics, Solar Energy Materials and Solar Cells, 91 (2007).
[4] Petritsch K.: Organic Solar Cell Architectures, PhD Thesis, Cambridge, Graz (2000).
Kolekcja BazTech
Identyfikator YADDA bwmeta1.element.baztech-article-BWAN-0018-0048