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http://yadda.icm.edu.pl:80/baztech/element/bwmeta1.element.baztech-article-BUJ7-0016-0015

Czasopismo

Polish Journal of Chemistry

Tytuł artykułu

Synthesis, Characterization and Antibacterial Activity of Triorganotin(IV) Complexes of 4-Methylphenol

Autorzy Sharma, N.  Kumar, V.  Thakur, M.  Kumari, M.  Chaudhry, S. C. 
Treść / Zawartość
Warianty tytułu
Języki publikacji EN
Abstrakty
EN The triorganotin(IV) com plex of com po si tion Ph3Sn(OArMe-4) has been synthesized in good yields by the reaction of Ph3SnCl with Me3SiOArMe-4/NaOArMe-4, while complexes of composition Me3Sn(OArMe-4) and n-Bu3Sn(OArMe-4) (where -OArMe-4 = -OC6H4CH3-4) have been obtained from the reaction of Me3SnCl and n-Bu3SnCl with 4-methylphenol in the presence of triethylamine in carbon tetrachloride. The complexes have been characterized by elemental analyses, molar conductance measurements, molecular weight determin tion and IR, 1H and 13C NMR and mass spectral studies. Thermal behaviour of the complexes has been studied by TG and DTA techniques. The organotin(IV) complexes have also been screened for their antibacterial properties and are found to exhibit appreciable activity. The reactions of the complexes with 2-, 3-, 4-cyanopyridines yielded 1:1 adducts as confirmed by physicochemical and IR spectral data.
Słowa kluczowe
EN trialkyl and triaryltinchlorides   4-methylphenol   spectral studies   antibacterial activity  
Czasopismo Polish Journal of Chemistry
Rocznik 2009
Tom Vol. 83, nr 12
Strony 2051--2065
Opis fizyczny Bibliogr. 47 poz., rys.
Twórcy
autor Sharma, N.
autor Kumar, V.
autor Thakur, M.
autor Kumari, M.
autor Chaudhry, S. C.
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