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http://yadda.icm.edu.pl:80/baztech/element/bwmeta1.element.baztech-article-BUJ7-0015-0078

Czasopismo

Polish Journal of Chemistry

Tytuł artykułu

Self-assembled Synthesis, Characterization and Antimicrobial Activity of Dinuclear Lanthanide Salicylaldimine Complexes Derived from Cadaverine

Autorzy Radecka-Paryzek, W.  Pospieszna-Markiewicz, I.  Kędzia, B. 
Treść / Zawartość
Warianty tytułu
Języki publikacji EN
Abstrakty
EN The new bimetallic lanthanide salicylaldimine complexes of the formula Ln2(H2L)3(NO3)6×2H2O, where Ln = La3+, Eu3+ or Gd3+ and H2L = N,N'- bis(salicyl -idene)-1,5-pentanediamine, are formed in a self-assembly process in volving the lanthanide template-induced one-pot Schiff base condensation reaction between salicylaldehyde and biogenic diamine cadaverine (1,5-pentanediamine). The complexes were characterized by spectroscopic methods (IR, 1H NMR, ESI-MS, UV-Vis, luminescence), and thermogravimetric and elemental analysis. The salicylaldimine with a potentially tetradentate N2O2 set of donor atms displays a rare coordination pattern acting as a neutral ligand using exclusively oxygens as donor atoms with out in volving the nitrogen atoms in the coordination. The europium(III) complex was tested for antimicrobial activity against Staph y lo coc cus aureus in a minimum inhibitory concentration (MIC) experiment.
Słowa kluczowe
EN lanthanides   salicylaldimine complexes   cadaverine   self-assembly   antimicrobial activity  
Wydawca Polskie Towarzystwo Chemiczne
Czasopismo Polish Journal of Chemistry
Rocznik 2009
Tom Vol. 83, nr 10
Strony 1693--1700
Opis fizyczny Bibliogr. 44 poz., rys.
Twórcy
autor Radecka-Paryzek, W.
autor Pospieszna-Markiewicz, I.
autor Kędzia, B.
  • Department of Bioinorganic Chemistry, Adam Mickiewicz University, Grunwaldzka 6, 60-780 Poznań, Poland, sepiol@ichf.edu.pl
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