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Polish Journal of Chemistry

Tytuł artykułu

Synthesis and Solid State Characterization of Organometallic Polymer of Ag(I) Using 2,2-Dimethyl-1,3-diisocyano Propane Ligand

Autorzy Al-Ktaifani, M. M.  Rukiah, M. K.  Shaaban, A. K. 
Treść / Zawartość
Warianty tytułu
Języki publikacji EN
EN 2,2-Dimethyl-1,3-diisocyano propane CNCH2C(CH3)2CH2NC was prepared and fully characterized by IR and multi-nuclear NMR spectroscopy. Treatment of CNCH2C(CH3)2CH2NC with AgCl afforded al most quantitatively highly in soluble powder. Its X-ray powder diffractional studies revealed a polymeric structure. In this structure the Ag centres are bridged with each of the two adjacent Ag neighbours by the bidentate ligands CNCH2(CH3)2CH2NC via the NC groups to form {Ag(CNCH2(CH3)2CH2NC)}n chains. The Cl- counter part an ions are cross linked the Ag centres of the chains to form a polymeric network {[Ag(CNCH2(CH3)2CH2NC)]Cl}n.
Słowa kluczowe
EN diisocyanide   Ag complex   powder X-ray structure   bidentate   polymeric structure   Rietveld refinements  
Wydawca Polskie Towarzystwo Chemiczne
Czasopismo Polish Journal of Chemistry
Rocznik 2008
Tom Vol. 82, nr 3
Strony 547--557
Opis fizyczny Bibliogr. 22 poz., rys.
autor Al-Ktaifani, M. M.
autor Rukiah, M. K.
autor Shaaban, A. K.
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