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http://yadda.icm.edu.pl:80/baztech/element/bwmeta1.element.baztech-article-BUJ6-0021-0045

Czasopismo

Polish Journal of Chemistry

Tytuł artykułu

Electrochemical Charging of Indium Hexacyanoferrate Films in DMSO and AcetonitrileWater Mixtures Containing Alkali Metal Cations

Autorzy Dzieniszewski, R.  Stroka, J.  Kulesza, P. J.  Galus, Z. 
Treść / Zawartość
Warianty tytułu
Języki publikacji EN
Abstrakty
EN Indium hexacyanoferrate films were investigated in water-acetonitrile and water- dimethylsulfoxide mixtures containing various alkali metal cations. The films, which were electrodeposited from the supporting electrolytes containing lithium cations, occurred to have fairly open structure permitting the transport of alkali metal cations in the solutions (mixtures) rich in nonaqueous solvents. The slopes of dependencies of formal potentials on the logarithms of concentrations of alkali metal cations were consistent with the predominant involvement of countercations in the redox reactions. But in the cases when the content of nonaqueous solvent was relatively high, the slopes were definitely lower than Nernstian (60mVper cation activity decade), thus implying a more complex mechanism of the reaction.
Słowa kluczowe
Wydawca Polskie Towarzystwo Chemiczne
Czasopismo Polish Journal of Chemistry
Rocznik 2001
Tom Vol. 75, nr 11
Strony 1753--1765
Opis fizyczny Bibliogr. 44 poz., rys.
Twórcy
autor Dzieniszewski, R.
autor Stroka, J.
autor Kulesza, P. J.
autor Galus, Z.
  • Department of Chemistry, University of Warsaw, Pasteura 1, PL-02-093 Warsaw, Poland
Bibliografia
Kolekcja BazTech
Identyfikator YADDA bwmeta1.element.baztech-article-BUJ6-0021-0045
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