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Polish Journal of Chemistry

Tytuł artykułu

Hydroxylation of Alkanes Using H2O2 or tert-BuOOH Catalyzed by Silica-based Fe(III) Interphase Catalysts

Autorzy Luo, Y.  Zhang, L.  Zong, M.  Ménage, S.  Fontecave, M. 
Treść / Zawartość
Warianty tytułu
Języki publikacji EN
EN Two novel silica-based organic-inorganic hybrid (interphase) Fe(III) catalysts have been successfully prepared by the flexible ligandmethod, characterized and applied to the efficient catalytic oxidation of various types of substrates using 30% H2O2 or tert-BuOOH under mild conditions. The catalysts can be recovered and reused for four reaction cycles with total turnover numbers being about 29 using cyclohexene as the substrate. The mechanism for the O-O bond cleavage was proposed based on the results in combination with previous experimental results.
Słowa kluczowe
EN methane monooxygenase   biomimetic hydroxylation   hydrogen peroxide   interphase catalyst  
Wydawca Polskie Towarzystwo Chemiczne
Czasopismo Polish Journal of Chemistry
Rocznik 2006
Tom Vol. 80, nr 8
Strony 1407--1414
Opis fizyczny Bibliogr. 31 poz., rys.
autor Luo, Y.
autor Zhang, L.
autor Zong, M.
autor Ménage, S.
autor Fontecave, M.
  • School of Biological Sciences and Biotechnology, and Department of Chemical Engineering, School of Chemical and Energy Engineering, South China University of Technology, Guangzhou 510640, P. R. China
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