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Polish Journal of Chemistry

Tytuł artykułu

Synthesis, Characterization and Crystal Structures of Diorganotin(IV) Complexes with 2-Mercapto-4-methyl-5-thiazoleacetic Acid

Autorzy Zhang, R.  Sun, F.  Ma, C.  Zhang, J. 
Treść / Zawartość
Warianty tytułu
Języki publikacji EN
EN The organotin(IV) complexes, [(C4H4NS2CH2CO2)R2Sn(OMe)OSnR2]2 (R =Me1, n-Bu 2, Ph 3, PhCH2 4), have been synthesized and characterized by IR and 1H NMR spectroscopy. The structures of 1 and 2 have also been determined by X-ray crystallography. The structure analyses show that both complexes 1 and 2 feature a centrosymmetric core arranged as a ladder. Links between pairs of tin atoms are afforded by mi2-methoxo groups and each carboxylate anion coordinates an exocyclic tin atom exclusively, in the monodentatemode.Moreover, the packing of complexes 1 and2 are stabilized by the hydrogen bonding interactions.
Słowa kluczowe
EN diorganotin   2-mercapto-4-methyl-5-thiazoleacetic acid   crystal structure  
Wydawca Polskie Towarzystwo Chemiczne
Czasopismo Polish Journal of Chemistry
Rocznik 2006
Tom Vol. 80, nr 3
Strony 367--376
Opis fizyczny Bibliogr. 23 poz.
autor Zhang, R.
autor Sun, F.
autor Ma, C.
autor Zhang, J.
  • Department of Chemistry, Liaocheng University, Liaocheng 252059, P. R. China
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