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http://yadda.icm.edu.pl:80/baztech/element/bwmeta1.element.baztech-79d16a4c-ed10-4c71-a739-f8fcd4dd8a1a

Czasopismo

Polish Journal of Chemical Technology

Tytuł artykułu

The oxidation of limonene at raised pressure and over the various titanium-silicate catalysts

Autorzy Wróblewska, A.  Makuch, E.  Miądlicki, P. 
Treść / Zawartość
Warianty tytułu
Języki publikacji EN
Abstrakty
EN This work presents the studies on the oxidation of limonene with hydrogen peroxide and tert-butyl hydroperoxide (TBHP) in the presence of : TS-2, Ti-Beta, Ti-MCM-41 and Ti-MWW catalysts, at the autogenic pressure and atmospheric pressure. The examination were performed at the following conditions: the temperature of 140°C (studies in the autoclave) and 80°C (studies in glass reactor), the molar ratio of limonene/oxidant (H2O2 or WNTB) = 1:1, the methanol concentration 80 wt%, the catalyst content 3 wt%, the reaction time 3 h and the intensity of stirring 500 rpm. The analysis of the results showed that in process not only 1,2-epoxylimonene was formed but also: 1,2-epoxylimonene diol, carveol, carvone and perillyl alcohol but for 1,2-epoxylimonene obtaining the better method was the method at the autogenic pressure and in the presence of TBHP.
Słowa kluczowe
EN limonene oxidation   hydrogen peroxide   TBHP  
Wydawca West Pomeranian University of Technology. Publishing House
Czasopismo Polish Journal of Chemical Technology
Rocznik 2015
Tom Vol. 17, nr 4
Strony 82--87
Opis fizyczny Bibliogr. 29 poz., rys., tab.
Twórcy
autor Wróblewska, A.
  • West Pomeranian University of Technology, Szczecin, Institute of Organic Chemical Technology, ul. Pulaskiego 10, 70-322 Szczecin, Poland, Agnieszka.Wroblewska@zut.edu.pl
autor Makuch, E.
  • West Pomeranian University of Technology, Szczecin, Institute of Organic Chemical Technology, ul. Pulaskiego 10, 70-322 Szczecin, Poland
autor Miądlicki, P.
  • West Pomeranian University of Technology, Szczecin, Institute of Organic Chemical Technology, ul. Pulaskiego 10, 70-322 Szczecin, Poland
Bibliografia
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Kolekcja BazTech
Identyfikator YADDA bwmeta1.element.baztech-79d16a4c-ed10-4c71-a739-f8fcd4dd8a1a
Identyfikatory
DOI 10.1515/pjct-2015-0072