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Journal of KONES

Tytuł artykułu

Waste tires as a source of valuable chemicals

Autorzy Ambrosewicz-Walacik, M.  Walacik, M. 
Treść / Zawartość
Warianty tytułu
Języki publikacji EN
EN The aim of the study was to determine the possibility of the isolation of valuable chemical compounds from pyrolysis oil obtained from the pyrolyzed waste car tires. Produced pyrolysis oil were subjected to a distillation process to isolate medium naphtha fraction average naphtha that contains limonene, which according to the literature data, can be used as an environmental friendly solvent in a number of cleaning agents. Considering the boiling point of limonene (176°C), the medium fraction of the separated oil was re-distilled to isolate compounds with temperature of boiling point between 174-177°C. The prepared sample was analysed by gas chromatography coupled with mass spectroscopy. Based on the chromatographic analysis, it was found that in a separate sample of pyrolysis oil the highest share constituted toluene, and then cyclobutane, benzene derivatives, which is essential in the chemical industry. The share of limonene was low (approx. 1%), what is explained by too high temperature of the pyrolytic process. The results of analysis and literature allow unequivocally state that in order to separate specific compounds from pyrolytic oil, parameters of this process should be first determined in pilot studies. In conclusion, it is believed that the pyrolysis of tires is suitable method of disposing of the waste, thereby obtaining products containing valuable compounds for the fuel and chemical industries.
Słowa kluczowe
EN waste tyres   pyrolysis   pyrolytic oil   chemical composition  
Wydawca Institute of Aviation
Czasopismo Journal of KONES
Rocznik 2016
Tom Vol. 23, No. 2
Strony 25--29
Opis fizyczny Bibliogr. 17 poz.
autor Ambrosewicz-Walacik, M.
  • University of Warmia and Mazury, Department of Mechatronics and ETI Sloneczna Street 46A, 10-710 Olsztyn, Poland tel.:+ 48 89 5245104, fax: +48 89 5245150 ,
autor Walacik, M.
  • University of Warmia and Mazury Department of Real Estate Management and Regional Development Prawochenskiego Street 15, 10-720 Olsztyn, Poland tel.: +48 89 5233886, fax: +48 89 5233832,
[1] Cunliffe, A. M., Williams, P. T., Composition of oils derived from the batch pyrolysis of tyres, Journal of Analytical and Applied Pyrolysis, Vol. 44, pp. 131-152, 1998.
[2] Jitkarnka, S., Chusaksri, B., Supaphol, P., Magaraphan, R., Influences of thermal aging on properties and pyrolysis products of tire tread compound, Journal of Analytical and Applied Pyrolysis, Vol. 80, pp. 269-276, 2007.
[3] Laresgoiti, M. F., Caballero, B. M., de Marco, I., Torres, A., Cabrero, M. A., Chomón, M. J., Characterization of the liquid products obtained in tyre pyrolysis, Journal of Analytical and Applied Pyrolysis, Vol. 71, pp. 917-934, 2004.
[4] Larsen, M. B., Schultz, L., Glarborg, P., Skaarup-Jensen, L., Dam-Johanes, K., Frandsen F., Herriksen U., Devolatilization characeristics of large particles of tyre rubber under combustion conditions, Fuel, Vol. 85, pp. 1335-1345, 2006.
[5] Li, S.Q., Yao, Q., Chi, Y., Yan, J. H., Cen, K. F., Pilot-scale pyrolysis of scrap tires in a continous rotary kiln reactor, Industrial & Enginnering Chemistry Research, Vol. 43, pp. 5133-5145, 2004.
[6] López, G., Olazar, M., Aguado, R., Bilbao, J., Continuous pyrolysis of waste tyres in a conical spouted bed reactor, Fuel, Vol. 89, pp. 1946-1952, 2010.
[7] Mui, E. L. K., Ko, D. C. K., McKay, G., Production of active carbons from waste tyres – a review, Carbon, Vol. 42, pp. 2789-2805, 2004.
[8] Pakdel, H., Pantea, D. M., Roy, C., Production of DL-limonene by vacuum pyrolysis of used tires, Journal of Analytical and Applied Pyrolysis, Vol. 57, pp. 91-107, 2001.
[9] Pakdel, H., Roy, C., Aubin, H., Jean, G., Coulombe, S., Formation of dl-limonene in used tire vacuum pyrolysis oils, Environmental Science & Technology, Vol. 25, pp. 1646-1649, 1991.
[10] Park, H. J., Dong, J. I., Jeon, J. K., Yoo, K. S., Yim, J. H, Sohn, J. M., Park, Y. K., Conversion of the pyrolytic vapor of radiata pine over zeolites, Journal of Industrial and Engineering Chemistry, Vol. 13, pp. 182-189, 2007.
[11] Quek, A., Balasubramanian, R., Liquefaction of waste tries by pyrolysis for oil and chemicals – a review, Journal of Analytical and Applied Pyrolysis, Vol. 101, pp. 1-16, 2013.
[12] Roy, C., Chaala, H., Darmstad, H., The vacuum pyrolysis of used tires End-uses for oil and carbon black products, Journal of Analytical and Applied Pyrolysis, Vol. 51, pp. 201-221,1999.
[13] Roy, C., Darmstad, H., Benallal, B., Amen-Chen, C., Characterization of naphtha and carbon black obtained by vacuum pyrolysis of polyisoprene rubber, Fuel Processing Technology, Vol. 50; pp. 87-103, 1997.
[14] Stanciulescu, M., Ikura, M., Limonene ethers from tire pyrolysis oil. Bart 1: Batch experiments. Journal of Analytical and Applied Pyrolysis, Vol. 75, pp. 217-225, 2006.
[15] Williams, P. T., Brindle, A. J., Aromatic chemicals from the catalytic pyrolysis of scrap tyres, Journal of Analytical and Applied Pyrolysis, Vol. 67, 143-164, 2003.
[16] Wojtowicz, M. A., Serio, M. A., Pyrolysis of scrap tires: can it be profitable? Chemical Technology, Vol. 26, pp. 48-53, 1996.
[17] Zhou, W., Widmer, W., Grohmann, K., Economic analysis of ethanol production from citrus peel waste, Proc. of the Florida State Horticultural Society, Vol. 120, pp. 310-315, 2007.
PL Opracowanie ze środków MNiSW w ramach umowy 812/P-DUN/2016 na działalność upowszechniającą naukę.
Kolekcja BazTech
Identyfikator YADDA bwmeta1.element.baztech-51ef23bc-736c-4564-8894-856f0d20f89b
DOI 10.5604/12314005.1213539